李首建

李首建

四川大學化學學院放射化學教研室主任,套用化學專業實驗室主任。 1977 年四川大學化學系放射化學專業畢業後留校任教至今。 1988.9-1991.9 蘇州醫學院放射衛生專業,獲碩士學位。 1999.12-2002.12 在 在美國北依利諾依斯大學 (Northern Illinois University, NIU) 化學及生物化學系固體材料化學研究組作客座研究員

基本介紹

  • 中文名:李首建
  • 職業:博士生導師,四川大學化學學院放射化學教研室主任
  • 畢業院校:四川大學化學系放射化學專業
  • 性別:男
簡介,研究方向,在研項目,主要業績,代表成果,

簡介

教授,博士生導師,四川大學化學學院放射化學教研室主任,套用化學專業實驗室主任。 1977 年四川大學化學系放射化學專業畢業後留校任教至今。 1988.9-1991.9 蘇州醫學院放射衛生專業,獲碩士學位。 1999.12-2002.12 在 在美國北依利諾依斯大學 (Northern Illinois University, NIU) 化學及生物化學系固體材料化學研究組作客座研究員。 作為項目負責人或主研人員參與完成了 有關的科研項目 19 項。 2001 年以來發表有關研究論文72 篇,其中, SCI 論文53 篇。
主講課程:
本科:核技術基礎及套用;應化設計實驗 (核輻射測量);天然藥物化學導論
研究生:結晶化學;核技術基礎及套用;研究專題(核廢物處理與處置)
研究生招生專業方向
  • 核燃料循環化學
  • 新型功能材料與放射化學分離
  • 錒系元素化學

研究方向

1. 放射化學分離材料與技術
2. 核廢物處理與處置
3. 新型固體功能材料的設計及合成

在研項目

( 2005 年後擔任負責人的國家及省級項目)
1. 一種新型三維開架微孔無機離子交換材料的合成和機理研究,國家自然科學基金
2. 硫屬沸石類多孔材料的合成及其在核廢物處理處置中的套用研究, 國家自然科學基金
3. 川紅花中功能性色素的連續分離製備工藝研究,四川省科技廳科學基金
4. 功能化炭基有序多孔材料及其在放射性核素分離中的套用,國家自然科學基金
5. 高性能水熱炭基固相萃取材料的合成及在關鍵核素分離中的套用研究,國家自然科學基金

主要業績

利用炭質材料具有絕大多數其它無機固體材料所不能比擬的優良特性:較大的比表面積,耐高溫,抗輻射,對各種酸鹼環境有較高穩定性,而且本身無毒,環境友好等,從事新型炭質功能材料的設計、合成及在放射性核素分離領域的套用研究。研究涉及的炭質材料包括傳統的活性炭、石墨和氧化石墨,以及新近開發的多孔炭、水熱炭、石墨烯和石墨烯量子點等。採用多種方法探討不同炭材料的表面化學性質、結構修飾方法和相應固相萃取劑的製備;考察合成材料對鈾等核素的吸附行為和吸附動力學、熱力學性能以及配位結構和配位(萃取)機制。
先後負責國家自然科學基金(4項)、中國核工業科學基金(3項)、四川省科技廳科學基金(3項)、中國工程物理研究院院外基金(2項)等19項科研項目,參加2項美國國家科學基金的研究工作。發表有關研究論文78篇,其中SCI論文59篇。
獲2013年度四川大學十佳師德獎。

代表成果

1. Ying Lan, Zhe Su, Xingliang Li, ZhaoqunJiang, Jun Jin, Jiali Xie, Shoujian Li*,Synthesis of a New Microporous Indium Sulphide and Its Capabilities to theSeparation of Strontium, J. Radioanalytical Nuclear Chemistry. 2007, 273(1):99-102.
2. Zhe Su, Xingliang Li, Ying Lan, Jintang Wen,Guangming Jin, Jiali Xie, Chong Zheng, Jun Jin, Shoujian Li*, A New Chalcogenide Ion Exchanging Material: PorousIndium Sulfide Built from Condensed [In10S18]6- T3 Supertetrahedral Clusters, Materials Letters. 2008, 62, 2802–2805.
3. Li Wang, Miao Feng, Chunxia Liu, Yongsheng Zhao,Shuqiong Li, Hang Wang, Liang Yan, Gan Tian, Shoujian Li*, Supporting of Potassium Copper Hexacyanoferrateon Porous Activated Carbon Substrate for Cesium Separation, Sep. Sc. Tech. 2009, 44(16), 4023–4035.
4. Miao Feng, Li Wang, Yongsheng Zhao, ChunxiaLiu, Zhen Chen, Liang Yan, Gan Tian, Hang Wang, Shoujian Li*, Synthesis andCharacterization of a New Activated carbon supported Ammonium Molybdophosphatecomposite and Its Cesium-selective Adsorption Properties, Radiochim Acta, 2010,98 (1), 39-44.
5. Yongsheng Zhao, Chunxia Liu, Miao Feng, ZhenChen, Shuqiong Li, Gan Tian, Li Wang, Jingbo Huang, Shoujian Li*, Solid phase extraction of uranium(VI)onto benzoylthiourea-anchored activated carbon, J. Hazard. Mater. 2010, 176, 119-124.
6. Liang Yan, Feng Zhao, ShoujianLi, Zhongbo Hu and Yuliang Zhao*, Low-toxic and safe nanomaterials bysurface-chemical design, carbon nanotubes, fullerenes, metallofullerenes, andgraphenes, Nanoscale, 2011, 3,362-382.
7. Gan Tian, Junxia Geng, Yongdong Jin, Chunli Wang, Shuqiong Li,Zhen Chen, Hang Wang, Yongsheng Zhao and ShoujianLi*, Sorption of uranium(VI) using oxime-grafted ordered mesoporous carbonCMK-5, J. Hazard. Mater. 2011,190, 422-450.
8. Shuqiong Li, Zhen Chen, Yongdong Jin, Shuihua Chen, Hang Wang,Junxia Geng, Qiang Song, Xiaodan Yang, Lijian Ma, Shoujian Li*, Zhi Qin*, and Chong Zheng, A new approach forpreparation of magnetite-graphite composite: intercalation of polyhydroxy ironcation into graphite oxide in L-arginine medium, Solid State Science, 2011, 13: 862-866.
9. Zhen Chen, Lijian Ma, Shuqiong Li, Junxia Geng, Qiang Song, JunLiu, Chunli Wang, Hang Wang, Juan Li, Zhi Qin,Shoujian Li*, Simple approach tocarboxyl-rich materials via low-temperature heat treatment of hydrothermalcarbon in air, Applied Surface Science, 2011 257(20), 8686– 8691.
10. Liang Yan, Yue Bing Zheng, Feng Zhao, Shoujian Li, Xingfa Gao, Bingqian Xu, Paul S. Weiss* and YuliangZhao*, Chemistry and physics of a single atomic layer: strategies andchallenges for functionalization of graphene and graphene-based materials, ChemSoc Rev, 2012, 41, 97–114.
11. Junxia Geng, Lijian Ma, Hang Wang, Jun Liu, Chiyao Bai, QiangSong, Juan Li, Min Hou, and Shoujian Li, Amidoxime-Grafted Hydrothermal Carbon Microspheres for HighlySelective Separation of Uranium, Journal of Nanoscience and Nanotechnology, 2012, 12 (9), 7354–7363.
12. Hang Wang, Lijian Ma, Kecheng Cao, Junxia Geng, Jun Liu, QiangSong, Xiaodan Yang, Shoujian Li*,Selective Solid-phase Extraction of Uranium by Salicylideneimine-functionalizedHydrothermal Carbon, J. Hazard. Mater. 2012, 229-230, 321-330.
13. Qiang Song, Lijian Ma, Jun Liu, Chiyao Bai, Junxia Geng, HangWang, Bo Li, Liyue Wang, Shoujian Li*,Preparation and Adsorption Performance of 5-azacytosine-functionalizedHydrothermal Carbon for Selective Solid-phase Extraction of Uranium, Journal ofColloid and Interface Science, 2012, 386, 291–299.
14. Jun Liu, Juan Li,Xiaodan Yang, Qiang Song, Chiyao Bai, Yong Shi, Lan Zhang, Chunxi Liu, Shoujian Li*, Lijian Ma*, Facile preparationof polyphenolic hydroxyl functionalized uranium-selective chelating sorbent:simple oxidation of styrene–divinylbenzene copolymer microparticles by Hummersmethod, Materials Letters, 2013, 97,117-180.
15. Hang Wang, Lijian Ma, Kecheng Cao, Junxia Geng, Jun Liu, Qiang Song, Xiaodan Yang, Shoujian Li*, Selective Solid-phase Extraction of Uranium by Salicylideneimine-functionalized Hydrothermal Carbon, J. Hazard. Mater. 2012, 229-230, 321-330.
16. Qiang Song, Lijian Ma, Jun Liu, Chiyao Bai, Junxia Geng, Hang Wang, Bo Li, Liyue Wang, Shoujian Li*, Preparation and Adsorption Performance of 5-azacytosine-functionalized Hydrothermal Carbon for Selective Solid-phase Extraction of Uranium, Journal of Colloid and Interface Science, 2012, 386, 291–299.
17. Jun Liu, Juan Li, Xiaodan Yang, Qiang Song, Chiyao Bai, Yong Shi, Lan Zhang, Chunxi Liu, Shoujian Li*, Lijian Ma*, Facile preparation of polyphenolic hydroxyl functionalized uranium-selective chelating sorbent: simple oxidation of styrene–divinylbenzene copolymer microparticles by Hummers method, Materials Letters, 2013, 97, 117-180.
18. Zhanjun Gu, Liang Yan, Gan Tian, Shoujian Li, Zhifang Chai, and Yuliang Zhao*, Recent Advances in Design and Fabrication of Upconversion Nanoparticles and Their Safe Theranostic Applications, Adv. Mater. 2013, 25(28) 3758–3779.
19. Xingliang Li, Wanjun Mu, Bijun Liu, Wenbin Zhong, Hongyuan Wei, Yuan, Jian, Zhengkun Zhong, Shunzhong Luo & Shoujian Li*, Adsorption kinetic, isotherm and thermodynamic studies of Sr2+ onto hexagonal tungsten oxide, J Radioanal Nucl Chem (2013) 298(1), 47-53.
20. Xiaodan Yang, Juan Li, Jun Liu, Yin Tian, Bo Li, Kecheng Cao, Songbai Liu, Min Hou, Shoujian Li* and Lijian Ma*, Simple Small Molecule Carbon Source Strategy for Synthesis of Functional Hydrothermal Carbon: Preparation of Highly Efficient Uranium Selective Solid Phase Extractant, Journal of Materials Chemistry A, 2014, 2(5), 1550-1559.
21. Bo Li, Lijian Ma, Yin Tian, Xiaodan Yang, Juan Li, Chiyao Bai, Xiaoyu Yang, Shuang Zhang, Shoujian Li, Yongdong Jin, A catechol-like phenolic ligand-functionalized hydrothermal carbon: One-pot synthesis, characterization and sorption behavior toward uranium, J. Hazard. Mater., 2014, 217, 41–49.
22. Chiyao Bai, Juan Li, Songbai Liu, Xiaoyu Yang, Xiaodan Yang, Yin Tian, Kecheng Cao, Ying Huang, Lijian Ma*, Shoujian Li*, In situ preparation of nitrogen-rich and functional ultramicro porous carbonaceous COFs by “segregated” microwave irradiation, Microporous and Mesoporous Materials, 2014, 197, 148–155.
23. Ying Huang, Chiyao Bai, Kecheng Cao, Yin Tian, Yue Luo, Chuanqin Xia, Songdong Ding, Yongdong Jin, Lijian Ma* and Shoujian Li*, Chaos to order: an eco-friendly way to synthesize graphene quantum dots. RSC Adv., 2014, 4, 43160–43165.
24. K. Cao, Y. Tian, Y. Zhang, C. Bai, Y. Luo, X. Zhao, L. Ma* and S. Li*, “Strategy and Mechanism for Controlling Direction of Defect Evolution in Graphene: Preparation of High-Quality Defect-Healed and Hierarchically Porous Graphene”, Nanoscale. 2014, DOI:10.1039/C4NR04453C.
25. Yin Tian, Jia Fu, Yi Zhang, Kecheng Cao, Chiyao Bai, Dongqi Wang, Shoujian Li,* Ying Xue,* Lijian Ma,* Chong Zheng*, Insight into the mechanism of solid phase extraction of uranium: a combined experimental and theoretical study, Inorg. Chem. 2014, submitted.

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