劉春元(暨南大學教授)

劉春元 2005年，哲學博士，Texas A&M University， 導師，F. Albert Cotton (科頓)2005-2006年，博士後研究，Texas A&M University。2007年，同濟大學化學學專業 ;2011-2016年，暨南大學生命科學技術學院化學系主任，2016-暨南大學化學與材料學院博士生導師。

基本介紹

• 中文名：劉春元
• 國籍：中國
• 性別：男
• 職稱： 暨南大學化學系教授

個人經歷

學習經歷：

1978–1981年：郴州師專，化學教育畢業。

1985–1988年：暨南大學化學系/中山大學，無機化學，碩士。

1999–2004年：美國Texas A&M大學化學系，導師，F. A. Cotton (科頓)，博士。

工作經歷：

1985–1996: 湘潭師範學院化學系，曾任副教授，省重點學科負責人，系主任。

1996–1999: 美國堪薩斯大學化學系Daryle H. Busch實驗室，客座研究員。

2004–2006: Texas A&M大學化學系F. Albert. Cotton實驗室，博士後研究。

2007–2011: 同濟大學 教授，博導。

2012–: 暨南大學 教授，博導。

研究興趣

分子電子器件

超分子組裝與分子識別

仿生無機化學

近年論文

主要論文：

1 .Optically Probing the Localized to Delocalized Transition in the Mo2-Mo2Mixed-valence Systems, Chem. Comm. 2017, 53, 3030-3033.

2.Study of asymmetrical mixed-valent Mo2-Mo2complexes in the class III regime，Suman Mallick, Dalton Trans, 2017, DOI: 10.1039/c6dt04915j, Tao Cheng, Miao Meng, Yu Yu Zhang and Chun Y. Liu,*

3.Photoinduced d electron transfer in phenylene bridged Mo2 dimers, Phys. Chem. Chem. Phys., 2017, 19, 1740-1745Tao Cheng, Xuan Xiao, Lei Zhang, Chun Y. Liu,* Li-Li Wang, Miao Meng, Fang Zhao, Hui Wang, Liang-Nian Ji。

4.Electronic Coupling between Two Covalently BondedDimolybdenum Units Bridged by a Naphthalene Group,Inorg. Chem.2016, 55, 6315–6322. Guang Yuan Zhu, Miao Meng, Ying Ning Tan, Xuan Xiao,Chun Y. Liu,*

5.Optical Determination of Electron Transfer Dynamics and Kinetics for Asymmetrical [Mo2]−ph−[Mo2] Systems, J. Phys. Chem. C,2016, 120, 12411−12422.Wei Yong Yu, Miao Meng, Hao Lei, Xue Dan He, and Chun Y. Liu,*

6.Tuning the Electronic Coupling and Electron Transfer in Mo2 Donor–Acceptor Systems by Variation of the Bridge Conformation Chem. Eur. J.2016, 22, 3115-3126.Mei Ting Kang, Miao Meng, Ying Ning Tan, Tao Cheng, Chun Y. Liu,*

7.Dimolybdenum dimers spaced by phenylene groups: The experimental models for study of electronic coupling,Inorg. Chim. Acta.2015424,. 63-74. Hao Lei, Xuan Xiao, Miao Meng, Tao Cheng, Yao Shu, Ying Ning Tan, Chun Y. Liu*,

8.Distinguishing the Strength of Electronic Coupling for Mo2-Containing Mixed-Valence Compounds within the Class III Regime, Chem. Eur. J. 2015, 21, 2353-2357. Tao Cheng, Ying Ning Tan, Yu Zhang, Yu Yu Zhang, Miao Meng, Hao Lei, Lu Chen, Chun Y. Liu*

9.Electronic Coupling in [Mo2]−Bridge−[Mo2] Systems with Twisted Bridges, Hong Li Zhang, Inorg. Chem. 2015, 54, 11314-11322. Guang Yuan Zhu, Gangyi Wang, Miao Meng, Chun Y. Liu,*Hao Lei.

10.Electronic Coupling and Electron Transfer between Two Dimolybdenum Units Spaced by a Biphenylene Group, J. Phys. Chem. C,2014, 118, 8308-8315. Xuan Xiao, Miao Meng, Hao Lei, Chun Y. Liu,*

11.Perturbation of the Charge Density between Two Bridged Mo2Centers: The Remote Substituent Effects, Inorg. Chem. 2014, 53, 9213−9221.Tao Cheng, Miao Meng, Hao Lei, andChun Y. Liu,*

12.Tuning the electronic coupling in Mo2–Mo2systems by variation of the coordinating atoms of the bridging ligands, Dalton Trans., 2014, 43, 14756–14765.Yao Shu,a Hao Lei, Ying Ning Tan, Miao Meng, Xiao Chun Zhang, Chun Y. Liu,*

13 “Spectroscopic Study of δ Electron Transfer between Two Covalently Bonded Dimolybdenum Units via a Conjugated Bridge: Adequate Complex Models to Test the Existing Theories for Electronic Coupling”, Chun Y. Liu,* Xuan Xiao, Miao Meng, Yu Zhang, and Mei Juan Han. J. Phys. Chem. C.2013 dx.doi.org/10.1021/jp406261w, Accepted.

14 “Abnormally Long-range Diamagnetic Anisotropy Induced by the Cyclic dp  Conjugation within a Six-membered Mo2/Chalcogen Ring”, Zhong Fei Tan, Chun Y. Liu*, Ziyun Li, Miao Meng and Ng Seik Weng, Inorg. Chem. 2012, 51, 2212

15 “Supramolecular assemblies of dimolybdenum transoids built by the Mo2-enhanced perfluorophenyl-perfluorophenyl synthons”, Li Juan Han, Li Yan Fan, Miao Meng, Xuefeng Wang and Chun Y. Liu*, Dalton Trans. 2011, 40，12832.

16 “Experimental and Theoretical Evidence of Aromatic Behavior in Heterobenzene-like Molecules having Metal-Metal Multiple Bonds”, Wenjuan Fang, Qiao He, Zhong Fei Tan, Chun Y. Liu,* Xin Lu,*and Carlos A. Murillo, Chemistry - A European Journal, 2011, 17, 10288.

17 “Enhanced Electronic Coupling in a Molecular Pair of Dimolybdenum Units Bridged by a Tetrathioterephthalate Dianion”, Mei Juan Han, Chun Y. Liu,* and Peng Fei Tian, Inorg. Chem. 2009, 48, 6347.

18 “Insertion of Ketenes into Lanthanocene n-Butylamide and Imidazolate Complexes” Ruiting Liu, Pengzhi Zheng, Linhong Weng, Xigeng Zhou* and Chun Y. Liu* J. Organomet. Chem. 2008, 693,1614.

19 “Enhancement in Electronic Communication upon Replacement of Mo–O by Mo–S Bonds in Tetranuclear Clusters of the Type [Mo2]2(μ-E—E)2, E = O or S” F. Albert Cotton, Zhong Li, Chun Y. Liu,* and Carlos A. Murillo,* Inorg. Chem. 2007, 46, 9294.

20 “Modulating Electronic Coupling Using O- and S-donor Linkers” F. Albert Cotton, Zhong Li, Chun Y. Liu,* Carlos A. Murillo,* Inorg. Chem. 2007, 46, 7840.

21 “A Deliberate Approach for the Syntheses of Heterometallic Suppramolecules Containing Dimolybdenum Mo24+ Species Coordinated to Metal Units” F. Albert Cotton, Zhong Li, Jia-Yi Jin, Chun Y. Liu,* Carlos, A. Murillo,* J. Chem. Soc., Dalton Trans., 2007, 2328.

22 “Electronic Localization versus Delocalization Determined by the Bonding of the Linker in an Isomer Pair” F. Albert Cotton,* Chun Y. Liu,* Carlos, A. Murillo,* Qinliang Zhao, Inorg. Chem. 2007, 46, 2604.

23 "A Fractional Bond Order of 1/2 in Pd25+Formamidinate Species; The Value of Very High Field EPR Spectra" John F. Berry,* Eckhard Bill, Eberhard Bothe, F. Albert Cotton,* Naresh S. Dalal,* Sergey A. Ibragimov, Narpinder Kaur, Chun Y. Liu, Carlos A. Murillo,* Saritha Nelluta, J. Micah North and Dino Villagrán, J. Am. Chem.Soc. 2007, 129, 1393.

24 “Molecular Pairs and A Propeller Containing Quadruply Bonded Dimolybdenum Units Linked by Polyamidate Ligands” F. Albert Cotton,* Zhong Li, Chun Y. Liu,* Carlos, A. Murillo,* Qinliang Zhao, Inorg. Chem. 2006, 45, 9795.

25 “An Isomeric Pair of Fluoride-Bridged Cyclic Dimolybdenum Triads” F. Albert Cotton,* Chun Y. Liu,* Carlos, A. Murillo,* Qinliang Zhao, Inorg. Chem. 2006, 45, 9480.

26 “Strong Electronic Communication by Direct Metal-metal Interaction in Molecules with Halide-Bridged Dimolybdenum Pairs” F. Albert Cotton,* Chun Y. Liu,* Carlos, A. Murillo,* Qingliang Zhao, Inorg. Chem. 2006, 45, 9493.

27 “Transition from a Nonbonding to a Bonding Interaction in a Tetranuclear [Mo2]2(µ-OR)4 Cluster” F. Albert Cotton,* Zhong Li, Chun Y. Liu, Carlos, A. Murillo,* Qingliang Zhao, Inorg. Chem. 2006, 45, 6387.

28 “Dimoylbdenum-Containing Molecular Triangles and Squares with Diamidate Linkers: Structural Diversity and Complexity” F. Albert Cotton,* Chun Y. Liu, Carlos, A. Murillo,* Xiaoping Wang, Inorg. Chem. 2006, 45, 2619.

29 “Strong Electronic Interaction between Two Dimolybdenum Units Linked by a Tetraazatetracene” F. Albert Cotton,* Zhong Li, Chun Y. Liu, Carlos, A. Murillo,* Inorg. Chem. 2006, 45, 767.

30 “Modeling Spin Interactions in a Cyclic Trimer and a Cuboidal Co4O4 Core with Co(II) In Tetrahedral and Octahedral Environments” John F. Berry, F. Albert Cotton,* Chun Y. Liu, Tongbu Lu, Carlos A. Murillo,* Boris S. Tsukerblat, Dino Villagrán and Xiaoping Wang, J. Am. Chem.Soc. 2005, 127, 4895.

31 “Strong Electronic Coupling between Dimolybdenum Units Linked by the N, N dimetheyl oxamidate Anion in a Molecule Having a Heteronaphthalene-like Structure.” F. Albert Cotton,* Chun Y. Liu, Carlos A. Murillo,* Dino Villagrán and Xiaoping Wang, J. Am. Chem. Soc, 2004, 126, 14822.

32 “Systematic Preparation of Mo24+ Building Blocks for Supramolecular Assemblies” F. Albert Cotton,* Chun Y. Liu and Carlos A. Murillo,* Inorg. Chem. 2004, 43, 2267.

33 “Fully Localized Mixed-Valence Oxidation Products of Molecules Containing Two Linked Dimolybdenum Units: An Effective Structural Criterion.” F. Albert Cotton,* Chun Y. Liu, Carlos A. Murillo* and Xiaoping Wang, J. Am. Chem. Soc, 2003, 125, 12945.

34 ”Modifying Electronic Communication in Dimolybdenum Units by Linkage Isomers of Bridged Oxamidate Dianions.” F. Albert Cotton,* Chun Y. Liu, Carlos A. Murillo,* Dino Villagrán and Xiaoping Wang, J. Am. Chem. Soc, 2003, 125, 13564.

35 ”Trapping Tetramethoxyzincate and -cobaltate(II) between Mo24+ Units.” F. A. Cotton,* Chun Y. Liu, Carlos A. Murillo and Xiaoping W, Inorg. Chem, 2003, 42, 4619.

36 “A Mixed-Valence Compound with One Unpaired Electron Delocalized over Four Molybdenum Atoms in A Cyclic Tetranuclear Ion.” F. A. Cotton,* Chun Y. Liu, Carlos A. Murillo* and Xiaoping Wang, Chem. Commun., 2003, 2190.

37 “How to Make a Major Shift in a Redox Potential: Ligand Control of the Oxidation State of Dimolybdenum Units.” F. Albert Cotton,* Lee M. Daniels, Chun Y. Liu, Carlos A. Murillo,* Arthur J. Schultz, and Xiaoping Wang, Inorg. Chem., 2002, 41, 4232.

38 “The First Designed Syntheses of Bis-dimetal Molecules in Which the Bridges Are Diamidate Ligands.” F. Albert Cotton,* Lee M. Daniels, James P. Donahue, Chun Y. Liu, and Carlos A. Murillo,* Inorg. Chem., 2002, 41, 1354.

39 “Steps on the Way to the First Dirhodium Tetracarboxylate with no Axial Ligand: Synthetic Lessons and a Plethora of Rh2(O2CR)4L2-n Compounds, n = 0, 1,2." F. Albert Cotton,* Elizabeth A. Hillard, Chun Y. Liu, Carlos A. Murillo,* Wenning Wang and Xiaoping Wang, Inorg. Chim. Acta, 2002, 337, 233.

承擔課題：

(1) 2013年（項目批准號21371074），國家自然科學基金面上項目：共價鍵合雙金屬D-B-A模型分子的合成及其電子偶合與電子傳遞研究。

（2）2009年（項目批准號90922010），國家自然科學基金重大研究項目（培育）：利用富電子鍵合雙金屬單元和有機多硫配體構造新型導電性分子材料。

(3) 2008年（項目批准號20871093），國家自然科學基金面上項目：非對稱橋連雙金屬中心間的電子耦合及分子內電子傳遞研究。

(4) 2008年，上海市教委重大創新科研項目：分子整流模型化合物—非對稱橋連雙金屬中心分子的合成及其物理化學性質研究。

（5）2007年（項目批准號20741004），國家自然科學基金（主任基金）：利用共價雙金屬踏輪式化合物實現對氣體分子的選擇性包囊。

所授課程：

1．《高等無機化學》（研究生）

2．《現代化學研究方法與技術》（研究生）。