陸慶全，博士，武漢大學高等研究院教授，博士生導師。
基本介紹
- 中文名：陸慶全
- 學位/學歷：博士
- 職業：教師
- 專業方向：基於電化學合成、光催化實現惰性化學鍵的可控重組
- 任職院校：武漢大學
研究方向,個人經歷,榮譽獎項,學術成果,
研究方向
主要研究方向：
自由基化學：基於電化學合成、光催化實現惰性化學鍵的可控重組
金屬有機化學：基於過渡金屬催化、仿生催化實現手性分子合成
物理有機化學：人工智慧在化學合成中的套用
個人經歷
科研及工作經歷：
2019.05— 武漢大學高等研究院，教授、博士生導師
2018.09—2019.04 美國聖路易斯華盛頓大學，博士後，合作導師：Prof. Kevin D. Moeller
2015.03—2018.09 德國明斯特大學，博士後、洪堡學者，合作導師：Prof. Frank Glorius
2011.09—2014.12 武漢大學，博士，導師：雷愛文教授
2008.09—2011.06 中國科學技術大學，碩士，導師：王官武教授
榮譽獎項
榮譽與獎勵:
德國明斯特大學博士後獎學金（2018）
湖北省優秀博士論文（2017）
德國亞歷山大·馮·洪堡獎學金、洪堡學者（2015）
愛思唯爾博士生獎全球45人名單（2014）
武漢大學十大珞珈風雲學子（2014）
武漢大學十大傑出青年(學生)（2014）
博士生國家獎學金（2013）
寶鋼優秀學生特等獎（2013）
學術成果
主要研究成果:
在氧氣引發的自由基反應以及廉價金屬催化的偶聯反應領域開展了系統性的研究；同時利用線上紅外、順磁、核磁、拉曼、同步輻射等技術手段對反應機理進行了較為深入的研究，並將發展的方法學套用到了生物活性分子、材料分子、藥物分子以及手性分子的合成等相關領域中，取得了系列性研究成果。以第一(含共一)作者身份在Angew. Chem., Int. Ed. (7篇)、J. Am. Chem. Soc. (1篇)、ACS Catal. (1篇)、Chem. Sci. (3 篇)等國際學術權威期刊上發表論文21篇，其中17篇論文為湯森路透JCR的Q1區論文，8篇第一(含共一)作者論文入選ESI高被引論文(Highly Cited Paper, top 1%)；長期受邀擔任Beilstein Journal of Organic Chemistry, Tetrahedron Letters, Chemistry - An Asian Journal, Organic & Biomolecular Chemistry, Chinese Journal of Chemistry等國際期刊的審稿人。
代表性論文：
21. Q. Lu#, S. Mondal#, S. Cembellín, S. Greßies, F. Glorius.* “Site-selective C–H Activation and Regiospecific Annulation Using Propargylic Carbonates”, Chem. Sci. 2019, 10, 6560-6564.
20. Q. Lu, S. Mondal, S. Cembellín, S. Singha, F. Glorius.* “Mn(I)/Ag(I) Relay Catalysis: Traceless Diazo-Assisted C(sp2)–H/C(sp3)–H Coupling to b-(Hetero)Aryl/Alkenyl Ketones”, Angew. Chem., Int. Ed. 2018, 57, 57, 10732-10736.
19. Q. Lu, S. Cembellín, S. Greßies, S. Singha, F. Glorius.* “Manganese(I)-Catalyzed C–H (2-Indolyl)methylation: Expedient Access to Diheteroarylmethanes”, Angew. Chem., Int. Ed. 2018, 57, 1399-1403. (Highly Cited Paper, 2018-2019)
18. Q. Lu#, S. Greßies#, S. Cembellín, F. J. R. Klauck, C. G. Daniliuc, F. Glorius.* “Redox-Neutral Manganese(I)-Catalyzed C–H Activation: Traceless Directing Group Enabled Regioselective Annulation”, Angew. Chem., Int. Ed. 2017, 56, 12778-12782. (Hot Paper Selected by the Editors, Highly Cited Paper, 2019)
17. Q. Lu, S. Greßies, F. J. R. Klauck, F. Glorius.* “Manganese(I)-Catalyzed Regioselective C-H Allenylation: Direct Access to 2-Allenylindoles”, Angew. Chem., Int. Ed. 2017, 56, 6660-6664. (Highly Cited Paper, 2018-2019)
16. Q. Lu, F. Glorius.* “Radical Enantioselective C(sp3)–H Functionalization”, Angew. Chem., Int. Ed. 2017, 56, 49-51. (Most Accessed Papers in 2017)
15. Q. Lu, F. J. R. Klauck, F. Glorius.* “Manganese-Catalyzed Allylation via Sequential C–H and C–C/C–Het Bond Activation”, Chem. Sci. 2017, 8, 3379-3383. (Highly Cited Paper, 2018-2019)
14. H. Wang#, Q. Lu#, C. Qian, C. Liu, W. Liu, K. Chen, A. Lei.* “Solvent Enabled Radical Selectivities: Controlled Syntheses of Sulfoxides and Sulfides”, Angew. Chem., Int. Ed. 2016, 55, 1094-1097. (Highly Cited Paper, 2018)
13. Q. Lu, S. Vásquez-Céspedes, T. Gensch, F. Glorius.* “Control over Organometallic Intermediate Enables Cp*Co(III) Catalyzed Switchable Cyclization to Quinolines and Indoles”, ACS Catal. 2016, 6, 2352-2356. (Highly Cited Paper, 2018-2019)
12. Q. Lu#, J. Zhang#, P. Peng, G. Zhang, H. Zhang, H. Yi, J. T. Miller, A. Lei.* “Operando X-ray absorption and EPR evidence for a single electron redox process in copper catalysis”, Chem. Sci. 2015, 6, 4851-4854.
11. Q. Lu, J. Zhang, G. Zhao, Y. Qi, H. Wang, A. Lei.* “Dioxygen-Triggered Oxidative Radical Reaction: Direct Aerobic Difunctionalization of Terminal Alkynes toward β‑Keto Sulfones”, J. Am. Chem. Soc. 2013, 135, 11481-11484. (Monthly Most Accessed Paper, Highly Cited Paper, 2018-2019)
10. Q. Lu, J. Zhang, F. Wei, Y. Qi, H. Wang, Z. Liu, A. Lei.* “Aerobic Oxysulfonylation of Alkenes Leading to Secondary and Tertiary b-Hydroxysulfones”, Angew. Chem., Int. Ed. 2013, 52, 7156-7159. (Highly Cited Paper, 2018-2019)
9. Z. Huang#, Q. Lu#, Y. Liu, D. Liu, J. Zhang, A. Lei.* “Regio- and Stereoselective Oxysulfonylation of Allenes”, Org. Lett. 2016, 18, 3940-3943.
8. Q. Lu#, P. Peng#, Y. Luo, Z. Zhao, M. Zhou, A. Lei.* “Copper-Catalyzed Aerobic Decarboxylation/Ketooxygenation of Electron-Deficient Alkenes”, Chem. Eur. J. 2015, 21, 18580-18583.
7. Q. Lu, Z. Liu, Y. Luo, G. Zhang, Z. Huang, H. Wang, C. Liu, J. T. Miller, A. Lei.* “Copper-/Cobalt-Catalyzed Highly Selective Radical Dioxygenation of Alkenes”, Org. Lett. 2015, 17, 3402-3405.
6. Q. Lu, H. Wang, P. Peng, C. Liu, Z. Huang, Y. Luo, A. Lei.* “Autoinductive thiolation/oxygenation of alkenes at room temperature”, Org. Chem. Front., 2015, 2, 908-912.
5. Q. Lu, J. Chen, C. Liu, Z. Huang, P. Peng, H. Wang, A. Lei.* “O2-Mediated C(sp2)−X Bonds Oxygenation: Autoxidative Carbon-Heteroatom Bonds Formation Using Activated Alkenes as Linkage”, RSC Adv., 2015, 5, 24494-24498.
4. Q. Lu, H. Yi, A. Lei.* “Autoxidative Coupling and Its Applications to C-H Functionalization”, Acta Chim. Sinica. 2015, 73, 1245-1249.
3. Q. Lu#, C. Liu#, Z. Huang, Y. Ma, J. Zhang, A. Lei.* “Relay cooperation of K2S2O8 and O2 in oxytrifluoromethylation of alkenes using CF3SO2Na”, Chem. Commun. 2014, 50, 14101-14104.
2. Q. Lu, C. Liu, P. Peng, Z. Liu, L. Fu, J. Huang, A. Lei.* “Copper-Catalyzed Trifluoromethylation-Initiated Radical Oxidative Annulation toward Oxindoles”, Asian J. Org. Chem. 2014, 3, 273-276.
1. G.-W. Wang,* Q.-Q. Lu, and J.-J. Xia,* “Three Types of Products Obtained Unexpectedly from the Reaction of Dimedone with Chalcones”, Eur. J. Org. Chem. 2011, 4429-4438.
