《鋁的電化學:從生產到套用》是2003年8月東北大學出版社出版的圖書，作者是李慶峰、邱竹賢。
基本介紹
- 書名：鋁的電化學
- 作者：李慶峰、邱竹賢
- ISBN：9787810549271
- 頁數：246
- 定價：25.00元
- 出版社：東北大學出版社
- 出版時間：2003-8
- 副標題：從生產到套用
內容簡介,圖書目錄,
內容簡介
《鋁的電化學:從生產到套用》試圖全面地闡述鋁的電化學理論和套用體系，尤其側重技術方面的開發現狀和最新進展。關於《鋁的電化學:從生產到套用》的構思，始於1991年，當時兩位作者還都在原東北工學院的有色金屬冶金系任教。後來作者之一的李慶峰到了丹麥技術大學化學系工作。1994年底，邱竹賢教授和已故的繆秀茳女士在訪問挪威的途中，順訪了哥本哈根。鋁的電化學在基礎理論和套用技術方面都具有重要的意義。作為元素電化學的一個獨特的分支，其所涉及的電解質體系範圍非常廣泛，有熔點在1000℃以上的金屬氟化物，有熔點介於幾十度到幾百度的金屬氯化物和溴化物，有室溫下的有機熔融鹽，有酸鹼鹽的水溶液體系，有各種有機溶液介質，還包括固態電解質。從套用的角度說來，鋁的電化學涉及到套用電化學的許多技術領域，包括金屬的電解生產，精煉，電鍍，陽極氧化和其他表面處理，一次電池和二次電池，電解電容器，腐蝕以及陰極保護等。
《鋁的電化學:從生產到套用》的大綱是在那次的訪問中擬定的。由於種種原因，全書直到2001年底才完稿。其中的幾章（第四章，第六章，第七章）是在最初的幾年裡完成的，這次最後定稿時，又做了補充和修改。書中的第二章和第三章，由邱竹賢教授撰寫，其餘章節由李慶峰完成，並最後定稿。
圖書目錄
Chapter 1 Introduction
1.1 Physical properties
1.2 Chemical properties
1.3 Electrochemistry of aluminum——systems and applications
Chapter 2 Aluminum Production
2.1 Stateoftheart of the HallH6roult process
2.2 Chemistry of molten electrolytes
2.2.1 Fundamental phase diagrams of the electrolyte
2.2.2 The ionic structure and electrode reactions
2.2.3 Physicochemical properties of electrolytes
2.2.4 Electrolytes in industrial cells
2.3 Aluminum electrolysis cells and related technology
2.3.1 General trends
2.3.2 Types of aluminum electrolysis cells
2.3.3 Cell construction
2.3.4 Preheating and startup
2.3.5 Cell technology
2.4 Electromagnetic forces and cell design
2.4.1 General
2.4.2 Busbars arrangement
2.4.3 Metal circulation patterns
2.4.4 Inert electrodes
2.4.5 Future cell design
2.5 Current efficiency
2.5.1 General
2.5.2 The metal re.oxidation reaction
2.5.3 Improvement of current efficiency in industrial cells
2.6 Energy consumption and savings
2.6.1 General
2.6.2 Energy balance
2.6.3 Heat loss distribution in aluminum electrolysis cells
2.6.4 Further improvements
2.7 Penetration of bath into the cathode lining and application
ofbarriers
2.7.1 PenetratiOn of bath
2.7.2 Observations of spent cell linings
2.7.3 Application of diffusion and penetration barriers
2.8 Alternative processes for aluminum production
2.8.1 Electrolysis of A1C13
2.8.2 Electrolysis of AIN
2.8.3 Electrolysis of A12S3
2.8.4 Carbothermal reduction of alumina and aluminosilicates
2.8.5 Comparison of energy requirements in various paths
References
Chapter 3 Aluminum Refining
3.1 Introduetion
3.2 Impurities from aluminum electrolysis cells
3.2.1 Nature and origin of impurities in the molten electrolyte
3.2.2 The decomposition potential of impurity elements
3.2.3 Behavior and balance of the impurities during electrolysis
3.2.4 Effects of using dry scrubber alumina as the cell feed
3.3 The three layer process
3.3.1 Electrodes and electrolytes
3.3.2 Electrode reactions
3.3.3 Cell operation and performance
3.4 The organoaluminum process
3.4.1 Organoaluminum electrolytes
3.4.2 The refining effect
References
Chapter 4 Electroplating of Aluminum
4.I Introduction
4.2 Aluminum plating from organic solvents
4.2.1 Aluminum hydride baths
4.2.2 Aluminum halide baths
4.2.3 Organoaluminum baths
4.3 Aluminum plating from room temperature molten salts
4.3.1 Room temperature molten salt systems
4.3.2 Haloaluminate systems
4.3.3 Mechanism of aluminum electroplating
4.3.4 Conclusive remarks
4.4 Aluminum plating from alkali chloroaluminate melts
4.4.1 Chemistry of alkali chloroaluminate melts
4.4.2 Cathodic process of aluminium deposition
4.4.3 Dendrite formation and inhibition
4.4.4 ElectrOplating of aluminum alloys
References
Chapter 5Surface Treatment of Aluminum
5.1 Introduction
5.2 Pretreatment
5.3 Anodizing and sealing
5.3.1 Mechanism of aluminum anodizing
5.3.2 Anodizing techniques
5.3.3 Equipments
5.3.4 Sealing techniques
5.3.5 Anodizing in molten salts
5.4 Electroplating of other metals on aluminum
5.4.1 General
5.4.2 Pretreatment
5.4.3 ElectrodepositiOn
5.4.4 Applications
5.5 Electropainting of aluminum
Rererences
Chapter 6 Aluminum for Energy Storage
6.1 Introduction
6.2 Aluminum batteries with aqueous electrolytes
6.2.1 General
6.2.2 Aluminum-manganese dioxide batteries
6.2.3 Aluminumsilver oxide battery
6.2.4 Aluminumhydrogen peroxide battery
6.2.5 Other batteries
6.3 Aluminum.air batteries
6.3.1 Introduction to metal/air batteries
6.3.2Aluminum anodes
6.3.3 Electrolytes and additives
6.3.4 Air/oxygen cathodes
6.3.5 System designs and operation
6.3.6 Applications
6.4 Aluminum batteries with nonaqueous electrolytes
6.4.1 Alkali.chloroaluminate melts
6.4.2 Room temperature molten salts
6.4.3 Sulfonebased electrolytes
References
Chapter 7 Aluminum Elcetrolytic Capacitor
7.1 Introduction
7.2 Aluminum foil
7.3 Liquid electrolytes
7.3.1 Electrolyte
7.3.2 Capacitor construction and applications
7.4 Organic semiconductive electrolytes
7.5 Solid polymer electrolytes
References
Chapter 8 Aluminum Corrosion
8.1 Introduction
8.2 Chemical corrosion
8.2.1 PotentialpH diagram of aluminumwater system
8.2.2 Al corrosion in aqueous media
8.2.3 Ai corrosion in gases
8.2.4 Al corrosion in molten media
8.3 Electrochemical corrosion
8.3.1 Pitting corrosion
8.3.2 Galvanic corrosion
8.3.3 Intergranular corrosion
8.3.4 Effects of alloying elements and solution additives
Rererences
Chapter 9 Cathodic Protection
9.1 Introduction
9.2Electrochemistry of cathodic protection
9.2.1 General
9.2.2 Impressed current technique
9.2.3 Sacrificial anode
9.3 Aluminum as sacrificial anode
9.4 Applications
References
1.2 Chemical properties
1.3 Electrochemistry of aluminum——systems and applications
Chapter 2 Aluminum Production
2.1 Stateoftheart of the HallH6roult process
2.2 Chemistry of molten electrolytes
2.2.1 Fundamental phase diagrams of the electrolyte
2.2.2 The ionic structure and electrode reactions
2.2.3 Physicochemical properties of electrolytes
2.2.4 Electrolytes in industrial cells
2.3 Aluminum electrolysis cells and related technology
2.3.1 General trends
2.3.2 Types of aluminum electrolysis cells
2.3.3 Cell construction
2.3.4 Preheating and startup
2.3.5 Cell technology
2.4 Electromagnetic forces and cell design
2.4.1 General
2.4.2 Busbars arrangement
2.4.3 Metal circulation patterns
2.4.4 Inert electrodes
2.4.5 Future cell design
2.5 Current efficiency
2.5.1 General
2.5.2 The metal re.oxidation reaction
2.5.3 Improvement of current efficiency in industrial cells
2.6 Energy consumption and savings
2.6.1 General
2.6.2 Energy balance
2.6.3 Heat loss distribution in aluminum electrolysis cells
2.6.4 Further improvements
2.7 Penetration of bath into the cathode lining and application
ofbarriers
2.7.1 PenetratiOn of bath
2.7.2 Observations of spent cell linings
2.7.3 Application of diffusion and penetration barriers
2.8 Alternative processes for aluminum production
2.8.1 Electrolysis of A1C13
2.8.2 Electrolysis of AIN
2.8.3 Electrolysis of A12S3
2.8.4 Carbothermal reduction of alumina and aluminosilicates
2.8.5 Comparison of energy requirements in various paths
References
Chapter 3 Aluminum Refining
3.1 Introduetion
3.2 Impurities from aluminum electrolysis cells
3.2.1 Nature and origin of impurities in the molten electrolyte
3.2.2 The decomposition potential of impurity elements
3.2.3 Behavior and balance of the impurities during electrolysis
3.2.4 Effects of using dry scrubber alumina as the cell feed
3.3 The three layer process
3.3.1 Electrodes and electrolytes
3.3.2 Electrode reactions
3.3.3 Cell operation and performance
3.4 The organoaluminum process
3.4.1 Organoaluminum electrolytes
3.4.2 The refining effect
References
Chapter 4 Electroplating of Aluminum
4.I Introduction
4.2 Aluminum plating from organic solvents
4.2.1 Aluminum hydride baths
4.2.2 Aluminum halide baths
4.2.3 Organoaluminum baths
4.3 Aluminum plating from room temperature molten salts
4.3.1 Room temperature molten salt systems
4.3.2 Haloaluminate systems
4.3.3 Mechanism of aluminum electroplating
4.3.4 Conclusive remarks
4.4 Aluminum plating from alkali chloroaluminate melts
4.4.1 Chemistry of alkali chloroaluminate melts
4.4.2 Cathodic process of aluminium deposition
4.4.3 Dendrite formation and inhibition
4.4.4 ElectrOplating of aluminum alloys
References
Chapter 5Surface Treatment of Aluminum
5.1 Introduction
5.2 Pretreatment
5.3 Anodizing and sealing
5.3.1 Mechanism of aluminum anodizing
5.3.2 Anodizing techniques
5.3.3 Equipments
5.3.4 Sealing techniques
5.3.5 Anodizing in molten salts
5.4 Electroplating of other metals on aluminum
5.4.1 General
5.4.2 Pretreatment
5.4.3 ElectrodepositiOn
5.4.4 Applications
5.5 Electropainting of aluminum
Rererences
Chapter 6 Aluminum for Energy Storage
6.1 Introduction
6.2 Aluminum batteries with aqueous electrolytes
6.2.1 General
6.2.2 Aluminum-manganese dioxide batteries
6.2.3 Aluminumsilver oxide battery
6.2.4 Aluminumhydrogen peroxide battery
6.2.5 Other batteries
6.3 Aluminum.air batteries
6.3.1 Introduction to metal/air batteries
6.3.2Aluminum anodes
6.3.3 Electrolytes and additives
6.3.4 Air/oxygen cathodes
6.3.5 System designs and operation
6.3.6 Applications
6.4 Aluminum batteries with nonaqueous electrolytes
6.4.1 Alkali.chloroaluminate melts
6.4.2 Room temperature molten salts
6.4.3 Sulfonebased electrolytes
References
Chapter 7 Aluminum Elcetrolytic Capacitor
7.1 Introduction
7.2 Aluminum foil
7.3 Liquid electrolytes
7.3.1 Electrolyte
7.3.2 Capacitor construction and applications
7.4 Organic semiconductive electrolytes
7.5 Solid polymer electrolytes
References
Chapter 8 Aluminum Corrosion
8.1 Introduction
8.2 Chemical corrosion
8.2.1 PotentialpH diagram of aluminumwater system
8.2.2 Al corrosion in aqueous media
8.2.3 Ai corrosion in gases
8.2.4 Al corrosion in molten media
8.3 Electrochemical corrosion
8.3.1 Pitting corrosion
8.3.2 Galvanic corrosion
8.3.3 Intergranular corrosion
8.3.4 Effects of alloying elements and solution additives
Rererences
Chapter 9 Cathodic Protection
9.1 Introduction
9.2Electrochemistry of cathodic protection
9.2.1 General
9.2.2 Impressed current technique
9.2.3 Sacrificial anode
9.3 Aluminum as sacrificial anode
9.4 Applications
References
