翁祖謙

翁祖謙，上海科技大學正教授。

基本介紹

• 中文名：翁祖謙
• 畢業院校：台灣大學
• 職稱：正教授

人物經歷

2019.07 上海科技大學教授

2015.04-2019.06 北京高壓科學研究中心研究員

2010.07-2015.04 Staff Scientist, SSRL, SLAC National Accelerator Laboratory

2006.04-2010.07 Scientist, Exp. Division, European Synchrotron Radiation Facility

2005.01-2006.03 Senior Res. Associate, BioCAT, CSRRI, Illinois Institute of Technology

2004.02-2004.12 Post-doc, Biophysics Res. Division, Univ. of Michigan at Ann Arbor

1997.09-2003.12 PhD, Chemistry, Univ. of Michigan at Ann Arbor

1993.09-1995.07 台灣大學化學系碩士

1989.09-1993.06 台灣大學化學系學士

研究方向

研究組主要是探討表界面間電子轉移和能量傳遞的超快過程，包括光致反應、光電催化、電化學反應等，研究其反應途徑與機理，以及生物酶蛋白的金屬氧化還原中心的功能結構。發展X射線譜學方法學（XAS、XES、IXS）與實驗探測技術，研製高能量分辨X射線光譜儀（圖 1,2,3）。在同步輻射設施和X射線自由電子雷射裝置套用X射線光譜技術，在原位反應條件下，結合時間分辨技術，配合第一原理計算，表征反應位點電子結構，進行能源材料的機理研究。

在研項目主要包括三個方面：（1）利用pump-probe探測技術研究光催化反應的電荷轉移動力學；（2）（光）電催化反應催化劑的製備、表征和機理研究；（3）用於X射線光譜儀的元件和材料的製備研究。

發表論文

45. “Resonant X-ray emission spectroscopy from broadband stochastic pulses at an X-ray free electron laser”. Communications Chemistry, 2021. 4(1).

44. “The five-analyzer point-to-point scanning crystal spectrometer at ESRF ID26”. Journal of Synchrotron Radiation, 2021. 28: p. 362-371.

43. “Effect of 3d/4p Mixing on 1s2p Resonant Inelastic X-ray Scattering: Electronic Structure of Oxo-Bridged Iron Dimers”. Journal of the American Chemical Society, 2021. 143(12): p. 4569-4584.

42. “Probing the Electronic Band Gap of Solid Hydrogen by Inelastic X-Ray Scattering up to 90 GPa”. Physical Review Letters, 2021. 126(3).

41. “Efficient approaches to solutions of partition function for condensed matters”. Journal of Physics-Condensed Matter, 2021. 33(11).

40. “Sulfur K beta X-ray emission spectroscopy: comparison with sulfur K-edge X-ray absorption spectroscopy for speciation of organosulfur compounds”. Physical Chemistry Chemical Physics, 2021. 23(8): p. 4500-4508.

39. “The Limitations of 5f Delocalization and Dispersion”. Applied Sciences-Basel, 2021. 11(9).

38. “Underlying simplicity of 5f unoccupied electronic structure”. Journal of Vacuum Science & Technology A, 2021. 39(4).

37. “Which phase of Ta2O5 being of the largest dielectric constant”. Journal of the American Ceramic Society, 2021.

36. “Femtosecond electronic structure response to high intensity XFEL pulses probed by iron X-ray emission spectroscopy”. Scientific Reports, 2020. 10(1).

35. “A versatile Johansson-type tender x-ray emission spectrometer”. Review of Scientific Instruments, 2020. 91(3).

34. “Towards the Quantification of 5f Delocalization”. Applied Sciences-Basel, 2020. 10(8).

33. “EXAFS as a probe of actinide oxide formation in the tender X-ray regime”. Surface Science, 2020. 698.

32. “Towards the Quantification of 5f Delocalization (vol 10, 2918, 2020)”. Applied Sciences-Basel, 2020. 10(12).

31. “Ultrathin transmission-type bent crystals for XFEL spectral diagnostic”. in International Conference on Optoelectronic and Microelectronic Technology and Application. 2020. Nanjing, PEOPLES R CHINA.

30. “A soft X-ray emission flat-field grating spectrometer for time-resolved spectroscopy”. in International Conference on Optoelectronic and Microelectronic Technology and Application. 2020. Nanjing, PEOPLES R CHINA.

29. “NpSe₂: a binary chalcogenide containing modulated selenide chains and ambiguous-valent metal”, Angew. Chem. Int. Ed., 2019, 58, 16130–16133.

28. “Soft X-ray spectroscopy with Transition-Edge Sensors at Stanford Synchrotron Radiation Lightsource beamline 10-1”, Rev. Sci. Instrum., 2019, 90, 113101.

27. “Comparison of Two Efficient Methods for Calculating Partition Functions”, Entropy, 2019, 21, 1050.

26. “Charge-Transfer-induced Interfacial Exchange Coupling at the Co/BiFeO₃ Interface”, Phys. Rev. Appl., 2019, 12, 044010.

25. “Diagram, Valence-to-Core, and Hypersatellite K beta X-ray Transitions in Metallic Chromium”, X-ray Spectrom., 2019, 48, 351–359.

24. “Revisiting the Phase Transition of Magnetite under Pressure”, J. Phys. Chem. C, 2019, 123, 21114–21119.

23. “What Retards the Response of Graphene based Gaseous Sensor”, Sens. Actuators A Phys., 2019, 295, 188–192.

22. “A New Model to Predict Optimum Conditions for Growth of 2D Materials on a Substrate”, Nanomaterials, 2019, 9, 978.

21. “Nature of Cobalt Species during the in situ Sulfurization of Co(Ni)Mo/Al₂O₃ Hydrodesulfurization Catalysts”, J. Synchrotron Rad., 2019, 26, 811–818.

20. “A High-Throughput Energy-Dispersive Tender X-ray Spectrometer for Shot-to-Shot Sulfur Measurements”, J. Synchrotron Rad., 2019, 26, 629–634.

19. “Separate measurement of the 5f_5/2 and 5f_7/2 unoccupied density of states of UO₂”, J. Electron Spectrosc. Relat. Phenom., 2019, 232, 100–104.

18. “Electronic Structure of Naturally Occurring Aromatic Carbon”, EnergyFuels., 2019, 33, 2099–2105.

17. “Electronic structure changes upon lithium intercalation into graphite – Insights from ex situ and operando X-ray Raman spectroscopy”, Carbon, 2019, 143, 371–377.

16. “Operando Observation of Chemical Transformations of Iridium Oxide During Photoelectrochemical Water Oxidation”, ACS Appl. Energy Mat., 2019, 2, 1371–1379.

15. “Initial metal-metal bond breakage detected by fs X-ray scattering in the photolysis of Ru₃(CO)₁₂ in cyclohexane at 400 nm”, Photochem. Photobiol. Sci., 2019, 18, 319–327.

14. “Carbon Core Electron Spectra of Polycyclic Aromatic Hydrocarbons”, J. Phys. Chem. A, 2018, 122, 5730–5734.

13. “Highly Active Surface Structure in Nanosized Spinel Cobalt-based Oxides for Electrocatalytic Water Splitting”, J. Phys. Chem. C, 2018, 122, 14447–14458.

12. “Surface- and Pressure-induced Bulk Kondo Breakdown in SmB₆”, Phys. Rev. B, 2018, 97, 235153.

11. “Ultrafast terahertz field control of electronic and structural interactions in vanadium dioxide”, Phys. Rev. B, 2018, 98, 045104.

10. “Oxygen Release Induced Chemomechanical Breakdown of Layered Cathode Materials”, Nano Lett., 2018, 18, 3241–3249.

9. “L-Edge Spectroscopy of Dilute, Radiation-Sensitive Systems using a Transition-Edge-Sensor Array”, J. Chem. Phys., 2018, 21, 214201.

8. “Soft X-Ray Second Harmonic Generation as an Interfacial Probe”, Phys. Rev. Lett., 2018, 120, 023901.

7. “Synchrotron X-ray Analytical Techniques for Studying Materials Electrochemistry in Rechargeable Batteries”, Chem. Rev., 2017, 117, 13123–13186.

6. “Ligand manipulation of charge transfer excited state relaxation and spin crossover in [Fe(2,2’-bipyridine)₂(CN)₂]”, Struct. Dynamics, 2017, 4, 044030.

5. “An Oxygen-Insensitive Hydrogen Evolution Catalyst Coated by a Molybdenum-based Layer for Overall Water Splitting”, Angew. Chem. Int. Ed., 2017, 56, 5780–5784.

4. “Operando Investigation on Au-MnOx thin films with improved activity for the oxygen evolution reaction”, Electrochimica Acta, 2017, 230, 22–28.

3. “Soft X-ray absorption spectroscopy investigation of the surface chemistry and treatments of copper indium gallium diselenide (CIGS)”, Sol. Energy Mater. Sol. Cells, 2017, 160, 390–397.

2. “Charge and spin-state characterization of cobalt bis(o-dioxolene) valence tautomers using Co Kβ x-ray emission and L-edge x-ray absorption spectroscopies”, Inorg. Chem., 2017, 56, 737–747.

1. “Manipulating charge transfer excited state relaxation and spin crossover in iron coordination complexes with ligand substation”, Chem. Sci., 2017, 8, 515–523.