柯卓鋒(Zhuofeng Ke)，男，1980年10月生，籍貫廣東，理學博士。中山大學“百人計畫”引進人才，教授，博士生導師。
基本介紹
- 中文名：柯卓鋒
- 外文名：Zhuofeng Ke
- 民族：中國
- 出生日期：1980年10月
工作經歷,教育經歷,榮譽與獎勵,科研方向,代表論文,
工作經歷
2019 - 至今中山大學，材料科學與工程學院，教授/博導
2016－2018 中山大學，材料科學與工程學院，副教授/博導
2012－2016 中山大學，化學院，副教授/博導
2009－2012 日本京都大學，福井謙一FIFC研究員
2016－2018 中山大學，材料科學與工程學院，副教授/博導
2012－2016 中山大學，化學院，副教授/博導
2009－2012 日本京都大學，福井謙一FIFC研究員
教育經歷
2005－2009 中山大學/美國北德克薩斯大學，物理化學，聯合培養博士
2002－2005 中山大學，高分子化學與物理，碩士
1998－2002 中山大學，化學系，本科
2002－2005 中山大學，高分子化學與物理，碩士
1998－2002 中山大學，化學系，本科
榮譽與獎勵
廣東省自然科學傑出青年(2015)
廣東特支計畫百千萬工程青年拔尖人才(2014)
福井謙一FIFC Fellow（2009-2012）
廣東特支計畫百千萬工程青年拔尖人才(2014)
福井謙一FIFC Fellow（2009-2012）
科研方向
1. 可再生能源、可再生資源與材料
2. 可再生催化與合成新方法
3. 理論計算精準催化劑設計
2. 可再生催化與合成新方法
3. 理論計算精準催化劑設計
代表論文
1. Zhang, M., Zhang, M.-T., Hou, C., Ke, Zhuo-Feng*, Lu T.-B.* Homogeneous Electrocatalytic Water Oxidation at Neutral pH by a Robust Macrocyclic Nickel(II) Complex. Angew. Chem., Int. Ed. DOI: 10.1002/anie.201406983 (2014).
2. Hou, C., Jiang J., Zhang S., Wang G., Zhang Z., Ke, Zhuofeng*, Zhao C.* Hydrogenation of Carbon Dioxide Using Half-Sandwich Cobalt, Rhodium, and Iridium Complexes: DFT Study on the Mechanism and Metal Effect. ACS Catal. 4, 2990–2997 (2014).
3. Zhou, Y.G., Zhang, X.P., Liang H.Y., Cao Z.K., Zhao X.Y., He Y.W., Wang S.L., Pang J.Y., Zhou Z.Y., Ke, Zhuofeng*, Qiu L.Q.* Enantioselective Synthesis of Axially Chiral Biaryl Monophosphine Oxides via Direct Asymmetric Suzuki Coupling and DFT Investigations of the Enantioselectivity. ACS Catal. 4, 1390–1397 (2014).
4. Petrovaa, G.P., Ke, Zhuofeng, Park S., Sugiyama H., Morokum K.* The origin of enantioselectivity for intramolecular Friedel–Crafts reaction catalyzed by supramolecular Cu/DNA catalyst complex. Chem. Phys. Lett. 600, 87-95 (2014).
5. Zhang, X., Ke, Zhuofeng, DeYonker N. J., Xu, H., Li Z.-F., Xu X., Zhang X., Su C.-Y., Phillips D. L., Zhao C.* Mechanism and Enantioselectivity of Dirhodium-Catalyzed Intramolecular C–H Amination of Sulfamate. J. Org. Chem. 78 (24), 12460–12468 (2013).
6. Liu, Y., Ma, L., Chen, W.-H.*, Park, H., Ke, Zhuofeng*, Wang, B*. Binding Mechanism and Synergetic Effects of Xanthone Derivatives as Noncompetitive α-Glucosidase Inhibitors: A Theoretical and Experimental Study. J. Phys. Chem. B 117 (43), 13464 -13471 (2013).
7. Ye, R.-R., Ke, Zhuo-Feng, Tan, C.-P., He, L., Ji, L.-N. & Mao, Z.-W. Histone-Deacetylase-Targeted Fluorescent Ruthenium(II) Polypyridyl Complexes as Potent Anticancer Agents. Chem. Eur. J. 19 (31), 10160 – 10169 (2013).
8. Xu, H. Y., Zhang, X. T., Ke, Zhuofeng, Li, Z. F., Xu, X. Y., Su, C. Y., Phillips, D. L. & Zhao, C. Y. Density functional theory study of the mechanism of zinc carbenoid promoted cyclopropanation of allenamides. Rsc Advances 3, 17131-17142 (2013).
9. Ke, Zhuofeng, Abe, S., Ueno, T., & Morokuma, Keiji. Catalytic Mechanism in Artificial Metalloenzyme: QM/MM Study of Phenylacetylene Polymerization by Rhodium Complex Encapsulated in apo-Ferritin.J. Am. Chem. Soc. 134 (37), 15418–15429 (2012).
10. Ke, Zhuofeng, Abe, S., Ueno, T., & Morokuma, Keiji. Rh-catalyzed Polymerization of Phenylacetylene: Theoretical Studies of the Reaction Mechanism, Regioselectivity and Stereoregularity. J. Am. Chem. Soc. 133 (20), 7926-7941 (2011). (JACS beta Select issue 13)
11. Liu, Y., Ke, Zhuofeng, Liu, Shuwen, Chen, Wen-Hua, Jiang, Shibo; Jiang, Zhi-Hong. "An Amphiphilic Conjugate Approach toward the Design and Synthesis of Betulinic Acid-Polyphenol Conjugates as Inhibitors of the HIV-1 gp41 Fusion Core Formation ". ChemMedChem 6 (9), 1654- 1664 (2011).
12. Gao, H., Ke, Zhuofeng, DeYonker N.J., Wang J., Xu H., Mao Z.-W., Phillips, D.L., Zhao C., Dinuclear Zn(II) Complex Catalyzed Phosphodiester Cleavage Proceeds via a Concerted Mechanism: A Density Functional Theory Study.J. Am. Chem. Soc. 133 (9), 2904–2915 (2011).
13. Ke, Zhuofeng & Cundari, T.R., Palladium-Catalyzed C-H Activation/C-N Bond Formation Reactions: DFT Study of Reaction Mechanisms and Reactive Intermediates. Organometallics 29 (4), 821-834 (2010). (Top10 Most Accessed Articles of Organometallics in 2010)
14. Lee, J.P., Ke, Zhuofeng, Ramirez, M.A., Gunnoe, T.B., Cundari, T.R., Boyle, P.D., & Petersen, J.L., Six-, Five-, and Four-Coordinate Ruthenium(II) Hydride Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis, Characterization, Fundamental Reactivity, and Catalytic Hydrogenation of Olefins, Aldehydes, and Ketones. Organometallics 28 (6), 1758-1775 (2009).
15. Guo, Z., Xue, J.D., Ke, Zhuofeng, Phillips, D.L., & Zhao, C.Y., Influence of Water Hydrogen Bonding on the Reactions of Arylnitrenium Ions With Guanosine: Hydrogen-Bonding Effects Can Favor Reaction at the C8 Site.J. Phys. Chem. B 113 (18), 6528-6532 (2009).
16. Foley, N.A., Lee, J.P., Ke, Zhuofeng, Gunnoe, T.B., & Cundari, T.R., Ru(II) Catalysts Supported by Hydridotris(pyrazolyl)borate for the Hydroarylation of Olefins: Reaction Scope, Mechanistic Studies, and Guides for the Development of Improved Catalysts. Acc. Chem. Res. 42 (5), 585-597 (2009).
17. Liu, Y., Ke, Zhuofeng, Cui, J.F., Chen, W.H., Ma, L., & Wang, B., Synthesis, inhibitory activities, and QSAR study of xanthone derivatives as alpha-glucosidase inhibitors. Bioorg. Med. Chem. 16 (15), 7185-7192 (2008).
18. Guo, Z., Ke, Zhuofeng, Phillips, D.L., & Zhao, C.Y., Intrinsic reaction coordinate analysis of the activation of CH4 by molybdenum atoms: A density functional theory study of the crossing seams of the potential energy surfaces.Organometallics 27 (2), 181-188 (2008).
19. Foley, N.A., Ke, Zhuofeng, Gunnoe, T.B., Cundari, T.R., & Petersen, J.L., Aromatic C-H activation and catalytic hydrophenylation of ethylene by TpRu{P(OCH2)(3)CEt}(NCMe)Ph. Organometallics 27 (13), 3007-3017 (2008).
20. Lin, X.F., Zhao, C.Y., Che, C.M., Ke, Zhuofeng, & Phillips, D.L., A DFT study on the mechanism of Rh-2(II,II)-catalyzed intramolecular amidation of carbamates. Chem. Asian J. 2 (9), 1101-1108 (2007).
21. Ke, Zhuofeng, Zhou, Y.B., Gao, H., Zhao, C.Y., & Phillips, D.L., On the mechanism and stereochemistry of chiral lithium-carbenoid-promoted cyclopropanation reactions. Chem. Eur. J. 13 (23), 6724-6731 (2007).
22. Ke, Zhuofeng, Zhao, C.Y., & Phillips, D.L., Methylene transfer or carbometalation? A theoretical study to determine the mechanism of lithium carbenoid-promoted cyclopropanation reactions in aggregation and solvation states. J. Org. Chem. 72 (3), 848-860 (2007).
23. Gao, H.Y.,Ke, Zhuofeng, Pei, L.X., Song, K.M., & Wu, Q., Drastic ligand electronic effect on anilido-imino nickel catalysts toward ethylene polymerization. Polymer 48 (25), 7249-7254 (2007).
24. Fang, R., Ke, Zhuofeng, Shen, Y., Zhao, C.Y., & Phillips, D.L., Concurrent cyclopropanation by carbenes and carbanions? A density functional theory study on the reaction pathways. J. Org. Chem. 72 (14), 5139-5145 (2007).
25. Zhou, Y.B., Ke, Zhuofeng, & Zhao, C.Y., A theoretical study on the mechanism of ruthenium(II)-catalyzed reaction of organic azide with alkyne. Acta Chim. Sin. 64 (20), 2071-2078 (2006).
26. Zhang, J.K., Ke, Zhuofeng, Bao, F., Long, J.M., Gao, H.Y., Zhu, F.M., & Wu, Q., Ethylene polymerization and oligomerization catalyzed by bulky beta-diketiminato Ni(II) and beta-diimine Ni(II) complexes/methylaluminoxane systems. J. Mol. Catal. A: Chem 249 (1-2), 31-39 (2006).
27. Ye, G.D., Ke, Zhuofeng, Yan, J.W., Zhao, T.Y., Zeng, Z.H., & Chen, Y.L., Low VOC bifunctional photoinitiator based on alpha-hydroxyalkylphenone structure. Polymer 47 (13), 4603-4612 (2006).
28. Li, Z.H., Ke, Zhuofeng, Zhao, C.Y., Geng, Z.Y., Wang, Y.C., & Phillips, D.L., A density functional theory study of aluminum carbenoid (CH3)(2)AlCH2X (X = Cl, Br, I) promoted cyclopropanation reactions compared to IMCH2I (M = Li, Sm, Zn) carbenoids. Organometallics 25 (15), 3735-3742 (2006).
29. Zhang, J.K., Gao, H.Y., Ke, Zhuofeng, Bao, F., Zhu, F.M., & Wu, Q., Investigation of 1-hexene isomerization and oligomerization catalyzed with beta-diketiminato Ni(II) bromide complexes/methylaluminoxane system. J. Mol. Catal. A: Chem 231 (1-2), 27-34 (2005).
