基本介紹
研究方向,主要成就,發表論文,社會任職,
研究方向
配位化學與功能分子材料
主要成就
於2013年6月獲得中山大學博士學位，期間多次獲得國家級、省級獎勵。曾公派赴法國國家科學研究院訪學一年，多次參加國內外學術會議，發表SCI論文十餘篇。
2013年7月被南京理工大學以副教授人才引進，並享受“紫金之星”科研資助項目綠色通道15萬經費支持。主持南京理工大學自主科研重大項目一項，經費20萬。主持南京大學配位化學國家重點實驗室開放基金項目一項，經費3萬。
發表論文
1. Li, X.; Zhang, D.; Qian, Y.; Liu, W.; Mathonière, C.; Clérac, R.*; Bao, X.* Chemical Manipulation of the Spin-Crossover Dynamics through Judicious Metal-Ion Dilution. J. Am. Chem. Soc.2023, 145 (17), 9564–9570.
2. Ou, S.; Wu, C.; Fan, Z.; Chen, J.; Tian, H.; Bao, X.* Cooperative Spin Crossover Near Room Temperature in Fe(II) Complexes Based on Acylhydrazone Ligands. Cryst. Growth Des.2023, 23 (5), 3275–3283.
3. Chen, T.-Y.; Cai, Y.; Jiang, S.-Q.; Cai, W.; Tong, M.-L.; Bao, X.* Light‐ and Chemical‐Stimuli‐Induced Isomerization of Donor−Acceptor Stenhouse Adducts. ChemPhotoChem2021, cptc.202100004 DOI: 10.1002/cptc.202100004.
4. Shen, K. Y.; Zhang, C. J.; Qu, L. Y.; Jiang, S. Q.; Zhang, Y.; Tong, M. L.; Bao, X.* Thermodriven, Acidity-Driven, and Photodriven Spin-State Switching in Pyridylacylhydrazoneiron(II) Complexes at or above Room Temperature. Inorg. Chem.2021, 60 (23), 18225–18233.
5. Yu, X.; Chen, T. Y.; Ye, Y. S.; Bao, X.* Spin Crossover in Mononuclear Fe(II) Complexes Based on a Tetradentate Ligand. J. Phys. Condens. Matter2020, 32 (17), 174001.
6. Ye, Y.-S.; Chen, X.-Q.; Shen, K.-Y.; Tong, M.-L.; Bao, X.* Acidity-Driven Bidirectional Room-Temperature Spin-State Switch and Fluorescence Modulation of a Mononuclear Fe(II) Complex. CCS Chem.2020, 2, 2350–2358.
7. Ye, Y. S.; Chen, X. Q.; De Cai, Y.; Fei, B.; Dechambenoit, P.; Rouzières, M.; Mathonière, C.; Clérac, R.; Bao, X.* Slow Dynamics of the Spin‐Crossover Process in an Apparent High‐Spin Mononuclear Fe II Complex. Angew. Chemie Int. Ed.2019, 58 (52), 18888–18891.
8. Chen, X.-Q.; Cai, Y.-D.; Jiang, W.; Peng, G.; Fang, J.-K.; Liu, J.-L.; Tong, M.-L.; Bao, X.* A Multi-Stimuli-Responsive Fe(II) SCO Complex Based on an Acylhydrazone Ligand. Inorg. Chem.2019, 58 (2), 999–1002.
9. Chen, X.-Q.; Cai, Y.-D.; Ye, Y.-S.; Tong, M.-L.; Bao, X.* Investigation of SCO Property–Structural Relationships in a Family of Mononuclear Fe(II) Complexes. Inorg. Chem. Front.2019, 6 (8), 2194–2199.
10. Cai, Y.-D.; Chen, T.-Y.; Chen, X. Q.; Bao, X.* Multiresponsive Donor–Acceptor Stenhouse Adduct: Opportunities Arise from a Diamine Donor. Org. Lett.2019, 21 (18), 7445–7449.
11. Hang, H.; Fei, B.; Chen, X. Q.; Tong, M. L.; Ksenofontov, V.; Gural’skiy, I. A.; Bao, X.* Multiple Spin Phases in a Switchable Fe(II) Complex: Polymorphism and Symmetry Breaking Effects. J. Mater. Chem. C2018, 6 (13), 3352–3361.
12. Fei, B.; Chen, X. Q.; Cai, Y. De; Fang, J.-K.; Tong, M. L.; Tucek, J.; Bao, X.* The Influence of NCE − (E = S, Se, BH3) Ligands on the Temperature of Spin Crossover in a Family of Iron( Ii ) Mononuclear Complexes. Inorg. Chem. Front.2018, 5 (7), 1671–1676.
13. Liu, X.; Zhou, J.; Bao, X.*; Yan, Z.; Peng, G.; Rouzières, M.; Mathonière, C.; Liu, J.-L.; Clérac, R. Mononuclear Fe(II) Complexes Based on the Methylpyrazinyl-Diamine Ligand: Chemical-, Thermo- and Photocontrol of Their Magnetic Switchability. Inorg. Chem.2017, 56 (20), 12148–12157.
14. Fei, B.; Zhou, J.; Yan, Z.; Shylin, S. I.; Ksenofontov, V.; Gural’skiy, I. A.; Bao, X.* Co–Co and Co–Fe Cyano-Bridged Pentanuclear Clusters Based on a Methylpyrazinyl-Diamine Tetradentate Ligand: Spin Crossover and Metal Substitution Effects. CrystEngComm2017, 19 (47), 7079–7082.
15. Luan, J.; Zhou, J.; Liu, Z.; Zhu, B.; Wang, H.; Bao, X.*; Liu, W.; Tong, M.-L.; Peng, G.; Peng, H.; Salmon, L.; Bousseksou, A. Polymorphism-Dependent Spin-Crossover: Hysteretic Two-Step Spin Transition with an Ordered [HS–HS–LS] Intermediate Phase. Inorg. Chem.2015, 54 (11), 5145–5147.
16. Zhou, J.; Zhu, B.-W.; Luan, J.; Liu, Z.; Fang, J.-K.; Bao, X.*; Peng, G.; Tucek, J.; Bao, S.-S.; Zheng, L.-M. In Air a Spin Crossover Active Iron(II) Complex of Amine/NCBH 3 Ligands Is Converted to a Low Spin Complex of Imine/CN Ligands. Dalton Trans.2015, 44 (47), 20551–20561.
社會任職
中國化學會會員、美國化學會會員
