余孝其，漢族，1965年7月生，籍貫四川資中，1991年加入中國共產黨；博士，教授，博士生導師。現任西華大學黨委常委、副校長。
基本介紹
- 中文名：余孝其
- 國籍：中國
- 出生地：四川資中
- 出生日期：1965年7月
- 職業：副校長
- 畢業院校：四川大學
- 主要成就：國家傑出青年基金獲得者、長江學者
- 性別：男
人物經歷,任免信息,學術兼職,研究方向,主要貢獻,獲獎記錄,
人物經歷
1983.09-1987.07 四川大學化學系讀本科，1987.09-1993.03 四川大學化學系有機化學專業碩、博連讀研究生。1993.04-1994.10四川大學化學系講師；1994.10-1996.11四川聯合大學化學系副教授；1996.11-1998.07四川聯合大學化學系副教授、系副主任；1998.04-2001.03香港大學化學系Research Assistant和Research Associate；1999.07-2005.07四川大學化學學院教授；2005.07-2010.12四川大學教授、科技處副處長；2010.12-2017.06四川大學教授、化學學院院長；2017.06-2018.08四川大學教授、黨委組織部部長；2018.08起任西華大學黨委常委、副校長。
主要從事生物螢光探針、生物醫學材料化學等領域的研究。共出版專著1部（Macrocyclic Polyamines: Synthesis and Applications, Published 2017 by Wiley-VCH）、參編教材和專著6章/節；發表SCI收錄論文360餘篇；獲授權專利12項；獲教育部自然科學一等獎1項，四川省科技進步獎二等獎2項、三等獎1項，四川省教學成果一等獎1項、二等獎1項。2000年被評為四川省有突出貢獻的博士學位獲得者；2003年入選教育部新世紀優秀人才；2006年被評為享受國務院特殊津貼專家；分別於2006年、2012年被評為四川省學術與技術帶頭人；2007年獲得國家傑出青年基金資助；2009年被聘為教育部長江學者特聘教授；2009年入選新世紀百千萬人才工程國家級人選。現任中國化學會理事，中國化學會化學生物學專業委員會委員，中國化學會超分子化學專業委員會委員，四川省化學化工學會副理事長。
任免信息
2018年7月，擬任省管高校副職。
學術兼職
現為中國化學會化學生物學專業委員會委員，中國監控化學品協會技術專家庫成員，綠色化學與技術教育部重點實驗室副主任，四川省禁化武技術專家，成都市反恐怖工作顧問。
是50餘種國際國內重要刊物的論文評審專家，包括Angew. Chem Int. Ed.、J. Am. Chem. Soc.、J. Org. Chem.、Org. Lett.、Chem. Commun.、Tetrahedron、Tetrahedron Lett.等國際化學領域主流期刊。
研究方向
1 、化學生物學（生物材料化學）。
2 、有機化學（生物有機化學）。
3 、綠色化學（綠色合成方法學）。
主要貢獻
共發表論文 200 余篇，其中 SCI 收錄 140 余篇。近五年發表的部分論文：
(1). Chen, X., Huang, Z., Chen, S.-Y., Li, K., Yu, X.-Q.* , Pu, L.*, Enantioselective Gel Collapsing: A New Means of Visual Chiral Sensing, J. Am. Chem. Soc. , 2010 , 132 , 7297–7299.
(2). Wen, J., Qin, S., Ma, L.-F., Dong, L., Zhang, J., Liu, S.-S., Duan, Y.-S., Chen, S.-Y., Hu, C.-W.*, Yu, X.-Q.* , Iron-Mediated Direct Suzuki - Miyaura Reaction: A New Method for the ortho -Arylation of Pyrrole and Pyridine, Org. Lett. , 2010 , 12 , 2694 - 2697.
(3). Xiang, Y.-Z., Feng, Z.-H., Zhang, J.*, Liao, Y.-L., Yu, C.-J., Yi, W.-J., Zhu, W.*, Yu, X.-Q.* , Linear cyclen-based polyamine as a novel and efficient reagent in gene delivery, Org. Biomol. Chem. , 2010 , 8 , 640–647.
(4). Chen, X., Chen, W., Wang, L., Yu, X.-Q. * , Huang, D.-S., Pu, L. *, Synthesis of a C 1 symmetric BINOL–terpyridine ligand and highly enantioselective methyl propiolate addition to aromatic aldehydes, Tetrahedron , 2010 , 66 , 1990–1993.
(5). Chen, X., Liu, Q., Sun, H.-B., Yu, X.-Q. * , Pu, L. *, A BINOL–terpyridine-based multi-task catalyst for a sequential oxidation and asymmetric alkylation of alcohols, Tetrahedron Lett. , 2010 , 51 , 2345–2347 .
(6). Huang, Y., Liu, J.-L., Zhang, J., Liu, Q., Hou, J.-T., Zhang, Y., Zhang, D.-W., Lu, Q.-S., Chen, S.-Y., Lin, H.-H.*, Yu, X.-Q.* , Interaction of bis-aryl functionalized molecules with nucleosides and nucleic acids , Sci. China Chem. , 2010 , 53 , 103–112.
(7). Zhou, L.-H., Yu, X.-Q. * , Pu, L. * , Reactivity of a propiolate dimer with nucleophiles and an efficient synthesis of dimethyl a-aminoadipate, Tetrahedron Lett. , 2010 , 51 , 425–427.
(8). Zhou, L.-H., Yu, X.-Q. * , Pu, L. * , Na-promoted aerobic oxidation of alcohols to ketones, Tetrahedron Lett. , 2010 , 51 , 475–477.
(9). Meng, X.-W., Qin, J., Liu, Y., Fan, M.-M., Li, B.-J.* , Zhang, S.* , Yu, X.-Q. , Degradable hollow spheres based on self-assembly inclusion, Chem. Commun. , 2010 , 46 , 643–645.
(10). Liu, P.-Y. , Li, K.* , Zhang, J. , Zhang, D.-W. , Lin, H.-H.* , Yu, X.-Q.* , Who Is the King? The a -Hydroxy- b -oxo- a , b -enone Moiety or the Catechol B Ring: Relationship between the Structure of Quercetin Derivatives and Their Pro-Oxidative Abilities, Chem. Biodivers. , 2010 , 7 , 236-244.
(11). Zhang, J., Meng, X.-G., Zeng, X.-C., Yu, X.-Q.* , Metallomicellar supramolecular systems and their applications in catalytic reactions, Coord. Chem. Rev. , 2009 , 253, 2166–2177.
(12). Yue, Y., Yu, X.-Q.* , Pu, L.*, Base-Catalyzed Highly Stereoselective Conversion of g -Hydroxy- a,b -acetylenic Esters to g -Acetoxy Dienoates, Chem. Eur. J. , 2009 , 15 , 5104-5107.
(13). Lu, Q.-S., Dong, L., Zhang, J., Li, J., Jiang, L., Huang, Y., Qin, S., Hu, C.-W., Yu, X.-Q.* , Imidazolium-Functionalized BINOL as a Multifunctional Receptor for Chromogenic and Chiral Anion Recognition, Org. Lett. , 2009 , 11 , 669-672.
(14). Li, K., He, T., Li, C., Feng, X.-W., Wang, N., Yu, X.-Q.* , Lipase-catalysed direct Mannich reaction in water: utilization of biocatalytic promiscuity to C-C bond formation in a “one-pot” synthesis, Green Chem. , 2009 , 11 , 777-779.
(15). Zhou, L.-H., Yu, X.-Q.* , Pu, L.*, Reactivity of γ -Hydroxy- α,β -acetylenic Esters with Amines: Facile Synthesis of the Optically Active 4-Amino-2(5 H )-furanones, J. Org. Chem. , 2009 , 74 , 2013–2017.
(16). Huang, Y., Zhang, Y., Zhang, J., Zhang, D.-W., Lu, Q.-S., Liu, J.-L., Chen, S.-Y., Lin, H.-H.*, Yu, X.-Q.* , Synthesis, DNA binding and photocleavage study of novel anthracene-appended macrocyclic polyamines, Org. Biomol. Chem. , 2009 , 7 , 2278-2285.
(17). Wu, B., Wen, J., Zhang, J., Li, J., Xiang, Y.-Z., Yu, X.-Q.* , One-Pot Van Leusen Synthesis of 4,5-Disubstituted Oxazoles in Ionic Liquids, Synlett , 2009 , (3) , 500-504.
(18). Zhou, L.-H., Yang. M., Zhou, H.*, Zhang, J., Li, K., Xiang, Y.-Z., Wang, N., Tian, Y.-F., Yu, X.-Q.* , Novel Reticular Cyclen-Based Polymer as Gene Vector in DNA Transfection, Chem. Biol. Drug Des. , 2009 ; 73 , 216–224.
(19). Wang, H.-Y., Li, C., Wang, N.*, Li, K., Feng, X.-W., He, T., Yu, X.-Q.*, Two-step enzymatic selective synthesis of water-soluble ketoprofen -saccharide conjugates in organic media, Bioorg. Med. Chem. , 2009 , 17 , 1905-1910.
(20). Xiang, Y.-Z., Wang, N., Zhang, J., Li, K., Zhang, Z.-W., Lin, H.-H.*, Yu, X.-Q.* , Novel Cyclen-Based Linear Polymer as a High-Affinity Binding Material for DNA Condensation, SCI China B , 2009 , 52 , 483-488.
(21). Xiang, Y.-Z., Zhou, L.-H., Jiang, N., Lin, H.-H.*, Yu, X.-Q.* , Synthesis of a novel linear polymer of macrocyclic polyamine copper (II) complex and its interaction with plasmid DNA, J. Enzyme Inhibition Med. Chem ., 2009 , 24, 315-319.
(22). Huang, Y., Chen, S.-Y., Zhang, J., Tan, X.-Y., Jiang, N., Zhang, J.-J., Zhang, Y., Lin, H.-H.*, Yu, X.-Q.* , Dinuclear copper (II) complexes of macrocyclic polyamines: Synthesis, characterization and DNA cleavage , Chem. Biodivers. , 2009 , 6 , 475-486.
(23). Li , K. , Wang , N . , Yang , F . , Zhang , Z . -W . , Zhou , L . -H . , Chen , S . -Y . , Lin , H . -H .* , Tian , Y . -F . , Yu , X . -Q . * , Cyclen- b ased side-chain homop olymer self-assembly with plasmid DNA : Protect ion of DNA from enzymatic degradation , Chem. Biodivers., 200 9 , 6 , 754-763 .
(24). Li, K., Zhou, L.-H., Zhang, J., Chen, S.-Y., Zhang, Z.-W., Zhang, J.-J., Lin, H.-H.*, Yu, X.-Q.* , “Self-activating” Chemical Nuclease: Ferrocenyl Cyclen Cu( II ) Complexes Act as Efficient DNA Cleavage Reagents in the Absence of Reductant, Eur. J. Med. Chem. , 2009 , 44 , 1768-1772.
(25). Yang, X.-B., Wang, L., Zhang, J., Zhang, Z.-W., Lin, H.-H.*, Zhou, L.-H., Yu, X.-Q.* , A New Schiff Base Copper (II) Complex Derived from Estrone and D-Glucosamine: Synthesis, Characterization and Its Interaction with DNA, J. Enzyme Inhibition Med. Chem. , 2009 , 23 , 125-130.
(26). Li, K., Zhang, J., Zhang, Z.-W., Xiang, Y.-Z., Lin, H.-H., Yu, X.-Q.* , Immobilization Cyclen Copper (II) on Merrifield Resin: Efficient Oxidative Cleavage of Plasmid DNA , J. Applied Polym. Sci. , 2009 , 111 , 2485-2492.
(27). Xiang, Y.-Z., Liao, Y.-L., Zhang, J.*, Zhang, D.-W., Chen, S.-Y., Lu, Q.-S., Zhang, Y., Lin, H.-H,*, Yu, X.-Q.* , Linear disulfide-containing low polymer as efficient DNA cleavage reagent , Bioorg. Med. Chem. Lett. , 2009 , 19 , 3458–3460.
(28). Wang, L., Zhang, J., Wang, N., Yang, X.-B., Wang, Q., Yu, X.-Q.* , Asymmetric Catalysis of Diels-Alder Cycloaddition of 2-Alkenoyl Pyridine with Cyclopentadiene by Binaphthol-Titanium Complex , Lett. Org. Chem., 2009 , 6, 392-396.
(29). Lu , Q.-S. , Huang, Y. , Li, J. , Zhang, Z.-W. , Lin, H.-H.* , Yu, X.-Q.* , The Effect of an Amino-Acid Bridge on Binding Affinity and Cleavage Efficiency of Pyrenyl-Macrocyclic Polyamine Conjugates toward DNA, Chem. Biodivers., 2009 , 6 , 1273-1282.
(30). Qin, J., Zhang, J., Wu, B., Zheng, Z.-G., Yang, M., Yu, X.-Q.* , Efficient and Mild Protocol for the Synthesis of 4(3)-Substituted 3(4)-Nitro-1 H -pyrroles and 3-Substituted 4-Methyl-2-tosyl-1 H pyrroles from Nitroolefins and Tosylmethyl Isocyanide in Ionic Liquids , Chinese J. Chem. , 2009 , 27 , 1782 - 1788.
(31). Li, J., Zhang, J., Lu, Q.-S., Yue, Y., Huang, Y., Zhang, D.-W., Lin, H.-H., Chen, S.-Y., Yu, X.-Q. * , Hydrolytic cleavage of DNA by urea-bridged macrocyclic polyamines, Eur. J. Med. Chem. , 2009 , 44 , 5090–5093.
(32). Chen, S.-Y., Zhang, J., Li, Y.-H., Wen, J., Bian, S.-Q., Yu, X.-Q. * , Cobalt-catalyzed homo-coupling of aryl and alkenyl bromide using atmospheric oxygen as oxidant, Tetrahedron Lett. , 2009 , 50 , 6795–6797.
(33). Feng, X.-W., Li, C., Wang, N.*, Li, K., Zhang, W.-W., Wang, Z., Yu, X.-Q.* , Lipase-catalysed decarboxylative aldol reaction and decarboxylative Knoevenagel reaction , Green Chem. , 2009 , 11 , 1933-1936.
(34). Yue, Y, Turlington, M., Yu, X.-Q.* , Pu, L.*, 3, 3' -Anisyl-Substituted BINOL, H4BINOL, and H8BINOL Ligands: Asymmetric Synthesis of Diverse Propargylic Alcohols and Their Ring-Closing Metathesis to Chiral Cycloalkenes, J. Org. Chem. , 2009 , 74 , 8681-8689.
(35). Wen, J., Zhang, J., Chen, S.-Y., Li, J., Yu, X.-Q.* , Iron-Mediated Direct Arylation of Unactivated Arenes, Angew. Chem. Int. Ed. , 2008 , 47 , 8897-8900.
(36). Zheng, Z.-G., Wen, J., Wang, N., Wu, B., Yu, X.-Q.* , N-Arylation of amines, amides, imides and sulfonamides with arylboroxines catalyzed by simple copper salt/EtOH system , Beilstein J. Org. Chem., 2008 , 4 , No. 40. doi:10.3762/bjo c.4.40.
( 37 ). Li, C., Feng , X . -W . , Wang , N . , Zhou , Y . -J ., Yu , X . -Q . * , Biocatalytic promiscuity: the first lipase-catalysed asymmetric aldol reaction, Green Chem. , 2008 , 10 , 616-618 .
(38). Yang, X.-B., Feng, J., Zhang, J., Wang, N., Wang, L., Liu, J.-L., Yu, X.-Q* , Highly Enantioselective Hetero-Diels ?- Alder Reaction of trans-1-Methoxy-2-methyl-3-trimethylsiloxybuta-1,3-diene with Aromatic and Aliphatic Aldehydes Catalyzed by 3-Substituted BINOL - Titanium Complex, Org. Lett. , 2008 , 10 , 1299-1302.
(39). Huang, Y., Lu, Q.-S., Zhang, J., Zhang, Z.-W., Zhang, Y., Chen, S.-Y., Li, K., Tan, X.-Y., Lin, H.-H.* , Yu, X.-Q. * , DNA cleavage by novel copper (II) complex and the role of b -cyclodextrin in promoting cleavage , Bioorg. Med. Chem. , 2008 , 16 , 1103-1110.
(40). Yang, X.-B., Feng, J., Zhang, J., Zhang, Z.-W., Lin, H.-H.* , Zhou, L.-H. , Yu, X.-Q. * , Synthesis, DNA binding and cleavage activities of the copper (II) complexes of estrogen-macrocyclic polyamine conjugates , Bioorg. Med. Chem. , 2008 , 16 , 3871-3877.
(41). Yang, F., Wang, L., Li, X., Shen, J., Wang, J., Yu, X.-Q.* , Improved Preparation of Nabumetone by Raney Ni Catalytic Hydrogenation , Lett. Org. Chem., 2008 , 5, 191-193.
(42). Huang, Q.-D., Chen, H., Zhou, L.-H., Huang, J., Wu, J., Yu X.-Q.* , A Novel Macrocyclic Polyamine Cationic Lipid Containing an Imidazolium Salt Group: Synthesis, Characterization and Its Transfection Activity as a Gene Delivery Vector, Chem. Biol. Drug. Des. , 2008 ; 71 , 224-229 .
(43). Tao, L., Yue, Y., Zhang, J., Chen, S.-Y., Yu, X.-Q.* , A Mild and Efficeint Method for N -Arylnucleobase Synthesis via the Cross-Coupling Reactions of Nucleobases with Arylboronic Acids Catalyzed by Simple Copper Salts , Helv. Chim. Acta , 2008 , 91 , 1008-1014.
(44). Wang, G.-Q., Zhang, J., Luo, S.-Z., Wang, N., Wei, H.-Y., Wang, W.-J., Yang, Y.-Q., Liu, G.-P., Yu, X.-Q.* , Synthesis and Primary Biological Evaluation of 188 ReN-NEMPTDD , J. Radioanaly. Nucl. Chem. , 2008 , 277 , 365-369.
(45). Zhao, Y.-C., Zhang, J., Wang, N., Yu, H., Yang, X.-B., Chen, S.-Y., Yu, X.-Q.* , Enantioselective Synthesis of 2, 6-Disubstituted Dihydropyrone Derivatives Catalyzed by TiCl 4 /BINOL/RONa System, Lett. Org. Chem. , 2008 , 5 , 391-395.
(46). Li, J., Yue, Y., Zhang, J., Lu, Q.-S., Li, K., Huang, Y., Zhang, Z.-W., Lin, H.-H.*, Wang, N., Yu, X.-Q. *, “Arm” effects of mononuclear cyclen copper complexes on DNA cleavage , Transit. Metal Chem. , 2008 , 33 , 759-765.
(47). Li, K., Zhang, J., Zhang, J.-J., Zhang, Z.-W., Zhuang, Z.-J., Xiao, D., Lin, H.-H.*, Yu, X.-Q.* , Ferrocene-Bridging Dinuclear Cyclen Copper( II ) Complexes as High Efficient Artificial Nucleases: Design, Synthesis and Interaction with DNA , Applied Organometal. Chem. , 2008 , 22 , 243-248.
(48). Li, C., Wang, H.-Y. Wang, N., * Fang, Y.-G., Chen, X., Yu, X.-Q. * , Highly regioselective enzymatic synthesis of polymerizable derivatives of methyl shikimate, Bioorg. Med. Chem. Lett. , 2007 , 17 , 6687-6690.
(49). Wang, R ., Lu, X. X .*, Yu, X. Q . *, Shi, L ., Sun, Y ., Acid-catalyzed solvent-free synthesis of 2-arylbenzimidazoles under microwave irradiation, J. Mol. Catal. A-Chem . 2007 , 266 (1-2) , 198-201.
(50). Tao, K ., Yu, X. Q .* , Liu, Y ., Shi, G. Y ., Liu, S. G ., Hou, T. P .*, Cloning, expression, and purification of insecticidal protein Pr596 from locust pathogen Serratia marcescens HR-3, Current Microbiology , 2007 , 55 (3) , 228-233.
(51). Huang, J., Huang, Q.-D., Zhang, J., Zhou, L.-H., Li, Q.-L., Li, K., Jiang, N., Lin, H.-H.*, Wu, J., Yu, X.-Q.* , Dinuclear Zinc (II) Complexes of Macrocyclic Polyamine Ligands Containing an Imidazolium Bridge: Synthesis, Characterization, and Their Interaction with Plasmid DNA, Int. J. Mol. Sci. 2007 , 8 , 606-617.
(52). He, L., Yu, J., Zhang, J., Yu, X.-Q.* , a -Amidation of cyclic ethers catalyzed by simple copper salts and a mild and efficient preparation method for a , v -aminoalcohols, Org. Lett. , 2007 , 9 , 2277-2280.
(53). Wang, Q., Chen, X., Tao, L., Wang, L., Xiao, D., Yu, X.-Q.* , Pu, L.*, Enantioselective Fluorescent Recognition of Amino Alcohols by a Chiral Tetrahydroxyl 1, 1' -Binaphthyl Compound, J. Org. Chem. , 2007 , 72, 97-101.
(54). Fang, Y.-G., Zhang, J., Chen, S.-Y., Jiang, N. , Lin, H.-H.*, Zhang, Y., Yu, X.-Q.* , Chiral multinuclear macrocyclic polyamine complexes: Synthesis, characterization and their interaction with plasmid DNA , Bioorg. Med. Chem. , 2007 , 15, 696-701.
(55). Wang, Q., Chen, S.-Y., Yu, X.-Q.* , Pu, L.*, 1, 1' -Binaphthyl ligands with bulky 3, 3' -tertiaryalkyl substitutes for the asymmetric alkyne addition to aromatic aldehydes, Tetrahedron , 2007 , 63, 4422-4428 .
(56). Zhao, Y.-C., Zhang, J., Huang, Y., Wang, G.-Q., Yu, X,-Q.* , DNA cleavage promoted by 2, 9-dimethyl-4, 7-diazadecane-2, 9-dithiol (DMDD) derivatives, Bioorg. Med. Chem. Lett. , 2007 , 17 , 2745-2748.
(57). Tan, X.-Y., Zhang, J., Huang, Y., Zhang, Y., Zhou, L.-H., Jiang, L., Lin, H.-H.*, Wang, N., Xia, C.-Q., Yu, X.-Q.* , Synthesis and DNA cleavage activities of the zinc(II), copper(II) and cobalt(II) complexes of benzocrown ether-fuctionalized 1,4,7,10-tetraazacyclododecane, Chem. Biodivers. , 2007 , 4 (9), 2190-2197.
(58). Liu, P.-Y., Jiang, N., Zhang, J., Wei, X., Lin, H.-H.*, Yu, X.-Q.* , The oxidative damage of plasmid DNA by ascorbic acid derivatives in vitro: The first research on the relationship between the structure of ascorbic acid and the oxidative damage of plasmid DNA, Chem. Biodivers. 2006 , 958-966.
(59). Gao, G., Wang, Q., Yu, X.-Q.* , Xie, R.-G., Pu, L.*, Highly Enantioselective Synthesis of g -Hydroxy- a , b -acetylenic Esters by Asymmetric AlkyneAddition to Aldehydes, Angew. Chem. Int. Ed. 2006 , 45 , 122-125.
(60). Zhao, Y.-C., Xiang, Y.-Z., Pu, L., Yang, M., Yu, X.-Q.* , Highly ? b ? - Selective Epoxidation of the D 5 - and D 4 -Unsaturated Steroids Catalyzed by the Silica-Supported Polyhalogenated Ruthenium Porphyrin , Applied Catal. A: General , 2006 , 301 , 176-181.
(61). Li, Q.-L., Huang, J., Wang, Q., Jiang, N., Xia, C.-Q., Lin, H.-H., Wu, J. ,* Yu, X.-Q. * , Monometallic complexes of 1,4,7,10-tetraazacyclododecane containing an imidazolium side: Synthesis, characterization, and their interaction with plasmid DNA, Bioorg. Med. Chem. , 2006 , 14 , 4151–4157.
(62). Xia, C.-Q., Jiang, N., Zhang, J., Chen, S.-Y., Lin, H.-H.*, Tan, X.-Y., Yue, Y., Yu, X.-Q.* , The Conjugates of Uracil-Cyclen Zn (II) Complexes: Synthesis, Characterization and Their Interaction with Plasmid DNA , Bioorg. Med. Chem. , 2006 , 14 , 5756-5764.
(63). Wang, X.-Y., Zhang, J., Li, K., Jiang, N., Chen, S.-Y., Lin, H.-H.*, Huang, Y., Ma, L.-J., Yu, X.-Q.* , Synthesis and DNA cleavage activities of mononuclear macrocyclic polyamine zinc(II), copper(II), cobalt(II) complexes which linked with uracil , Bioorg. Med. Chem. , 2006 , 14 , 6745-6751.
(64). Zheng, L., Zhang, S., Yu, X. , Zhao, L., Gao, G., Yang, X., Duan, H., Cao, S. , Enhancement of enantioselectivity in lipase-catalyzed resolution of N -(2-ethyl-6-methylphenyl)alanine by additives, J. Mol. Catal. B: Enzym. 2006 , 38 , 17-23.
(65). Yu, Y., Zhou, W.-C., Zhang, J., Zhang, M., Xu, D.-Y., Tang, Y., Li, B.-G., Yu, X.-Q.* , Novel Synthetic Route of a Pivotal Intermediate for the Synthesis of 1 b -Methyl Carbapenem Antibiotics, Org. Process Res. Dev. , 2006 , 10 , 829-832.
(66). Jiang, F.-B., Huang, L.-Y., Meng, X.-G., Du, J., Yu, X.-Q.* , Zhao, Y.-F., Zeng, X.-C.*, Metallomicellar catalysis: Hydrolysis of phosphate monoester and phosphodiester by Cu(II), Zn(II) complexes of pyridyl ligands in CTAB micellar solution, J. Colloid Interface Sci. , 2006 , 303 , 236-242.
(67). Qiao, R.-Z., Zhang, Z., Ju, Y. , Xia, C.-Q., Yu, X.-Q. , Zhao, Y.-F., Electrospray Ionization Mass Spectral Characteristics of Polyamide Containing 1,4,7,10-Tetraazacyclododecane, Chinese J. Chem. , 2006 , 24 , 923-928.
(68). Yue, Y., Zheng, Z.-G., Wu, B., Xia, C.-Q., Yu X.-Q.* , Copper-Catalyzed Cross-Coupling Reactions of Nucleobases with Arylboronic Acids: An Efficient Access to N -Arylnucleobases, Eur. J. Org. Chem., 2005 , 5154–5157.
(69). Peng, W., Liu, P.-Y., Jiang, N., Lin, H.-H., Zhang, G.-L., Liu, Y., Yu, X.-Q.* , Dinuclear macrocyclic polyamine zinc(II) complexes linked with X exible spacers: Synthesis, characterization, and DNA cleavage, Bioorg. Chem. , 2005 , 33, 374–385.
(70). Xiang, Q.-X.; Zhang, J.; Liu, P.-Y.; Xia, C.-Q.; Zhou, Z.-Y.; Xie, R.-G.; Yu, X.-Q.* , Dinuclear macrocyclic polyamine zinc (II) complexes: Syntheses, characterization and their interaction with plasmid DNA, J. Inorg. Biochem. , 2005 , 99(8) , 1661-1669.
(71). Li, Z.-C.; Zhang, J.; Hu, W.-H.; Chen, Z.-Y.; Yu, X.-Q.* , Rhodium Acetate-Mediated Epoxidation from the Reaction of Diazobenzylphosphonates with Aldehydes and Ketones: A Convenient and Highly Steroselective Synthetic Method for cis-1,2-Epoxypropylphosphonates, Synlett , 2005 , (11) , 1711-1715.
(72). Jiang, F.-B.; Jiang, B.-Y.; Cao, Y.-S.; Meng, X.-G.; Yu, X.-Q.* ; Zeng, X.-C., Metallomicellar catalysis: Hydrolysis of phosphate monoester by Cu(II), Zn(II), Ni(II) and Co(II) complexes of pyridyl ligands in CTAB micellar solution, Colloids and Surfaces A: Physicochem. Eng. Aspects , 2005 , 254 , 91-97.
(73). Chen, S.-Y., Huang, Y., Zhang, G.-L., Cheng, H., Xia, C.-Q., Ma, L.-J., Yu, H., Yu, X.-Q. *, Synthesis of a cyclen-functionalized? a -amino acid and its incorporation into peptide sequence, Synthesis , 2005 , (6), 888-892.
(74). Ma, L.-J., Zhang, G.-L., Chen, S.-Y., Wu, B., You, J.-S., Xia, C.-Q., Yu, X.-Q. *, The First Synthesis of Chiral PNA Monomer-Cyclen Conjugates , J. Peptide Sci. , 2005 , 11 , 812-817.
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(1). Chen, X., Huang, Z., Chen, S.-Y., Li, K., Yu, X.-Q.* , Pu, L.*, Enantioselective Gel Collapsing: A New Means of Visual Chiral Sensing, J. Am. Chem. Soc. , 2010 , 132 , 7297–7299.
(2). Wen, J., Qin, S., Ma, L.-F., Dong, L., Zhang, J., Liu, S.-S., Duan, Y.-S., Chen, S.-Y., Hu, C.-W.*, Yu, X.-Q.* , Iron-Mediated Direct Suzuki - Miyaura Reaction: A New Method for the ortho -Arylation of Pyrrole and Pyridine, Org. Lett. , 2010 , 12 , 2694 - 2697.
(3). Xiang, Y.-Z., Feng, Z.-H., Zhang, J.*, Liao, Y.-L., Yu, C.-J., Yi, W.-J., Zhu, W.*, Yu, X.-Q.* , Linear cyclen-based polyamine as a novel and efficient reagent in gene delivery, Org. Biomol. Chem. , 2010 , 8 , 640–647.
(4). Chen, X., Chen, W., Wang, L., Yu, X.-Q. * , Huang, D.-S., Pu, L. *, Synthesis of a C 1 symmetric BINOL–terpyridine ligand and highly enantioselective methyl propiolate addition to aromatic aldehydes, Tetrahedron , 2010 , 66 , 1990–1993.
(5). Chen, X., Liu, Q., Sun, H.-B., Yu, X.-Q. * , Pu, L. *, A BINOL–terpyridine-based multi-task catalyst for a sequential oxidation and asymmetric alkylation of alcohols, Tetrahedron Lett. , 2010 , 51 , 2345–2347 .
(6). Huang, Y., Liu, J.-L., Zhang, J., Liu, Q., Hou, J.-T., Zhang, Y., Zhang, D.-W., Lu, Q.-S., Chen, S.-Y., Lin, H.-H.*, Yu, X.-Q.* , Interaction of bis-aryl functionalized molecules with nucleosides and nucleic acids , Sci. China Chem. , 2010 , 53 , 103–112.
(7). Zhou, L.-H., Yu, X.-Q. * , Pu, L. * , Reactivity of a propiolate dimer with nucleophiles and an efficient synthesis of dimethyl a-aminoadipate, Tetrahedron Lett. , 2010 , 51 , 425–427.
(8). Zhou, L.-H., Yu, X.-Q. * , Pu, L. * , Na-promoted aerobic oxidation of alcohols to ketones, Tetrahedron Lett. , 2010 , 51 , 475–477.
(9). Meng, X.-W., Qin, J., Liu, Y., Fan, M.-M., Li, B.-J.* , Zhang, S.* , Yu, X.-Q. , Degradable hollow spheres based on self-assembly inclusion, Chem. Commun. , 2010 , 46 , 643–645.
(10). Liu, P.-Y. , Li, K.* , Zhang, J. , Zhang, D.-W. , Lin, H.-H.* , Yu, X.-Q.* , Who Is the King? The a -Hydroxy- b -oxo- a , b -enone Moiety or the Catechol B Ring: Relationship between the Structure of Quercetin Derivatives and Their Pro-Oxidative Abilities, Chem. Biodivers. , 2010 , 7 , 236-244.
(11). Zhang, J., Meng, X.-G., Zeng, X.-C., Yu, X.-Q.* , Metallomicellar supramolecular systems and their applications in catalytic reactions, Coord. Chem. Rev. , 2009 , 253, 2166–2177.
(12). Yue, Y., Yu, X.-Q.* , Pu, L.*, Base-Catalyzed Highly Stereoselective Conversion of g -Hydroxy- a,b -acetylenic Esters to g -Acetoxy Dienoates, Chem. Eur. J. , 2009 , 15 , 5104-5107.
(13). Lu, Q.-S., Dong, L., Zhang, J., Li, J., Jiang, L., Huang, Y., Qin, S., Hu, C.-W., Yu, X.-Q.* , Imidazolium-Functionalized BINOL as a Multifunctional Receptor for Chromogenic and Chiral Anion Recognition, Org. Lett. , 2009 , 11 , 669-672.
(14). Li, K., He, T., Li, C., Feng, X.-W., Wang, N., Yu, X.-Q.* , Lipase-catalysed direct Mannich reaction in water: utilization of biocatalytic promiscuity to C-C bond formation in a “one-pot” synthesis, Green Chem. , 2009 , 11 , 777-779.
(15). Zhou, L.-H., Yu, X.-Q.* , Pu, L.*, Reactivity of γ -Hydroxy- α,β -acetylenic Esters with Amines: Facile Synthesis of the Optically Active 4-Amino-2(5 H )-furanones, J. Org. Chem. , 2009 , 74 , 2013–2017.
(16). Huang, Y., Zhang, Y., Zhang, J., Zhang, D.-W., Lu, Q.-S., Liu, J.-L., Chen, S.-Y., Lin, H.-H.*, Yu, X.-Q.* , Synthesis, DNA binding and photocleavage study of novel anthracene-appended macrocyclic polyamines, Org. Biomol. Chem. , 2009 , 7 , 2278-2285.
(17). Wu, B., Wen, J., Zhang, J., Li, J., Xiang, Y.-Z., Yu, X.-Q.* , One-Pot Van Leusen Synthesis of 4,5-Disubstituted Oxazoles in Ionic Liquids, Synlett , 2009 , (3) , 500-504.
(18). Zhou, L.-H., Yang. M., Zhou, H.*, Zhang, J., Li, K., Xiang, Y.-Z., Wang, N., Tian, Y.-F., Yu, X.-Q.* , Novel Reticular Cyclen-Based Polymer as Gene Vector in DNA Transfection, Chem. Biol. Drug Des. , 2009 ; 73 , 216–224.
(19). Wang, H.-Y., Li, C., Wang, N.*, Li, K., Feng, X.-W., He, T., Yu, X.-Q.*, Two-step enzymatic selective synthesis of water-soluble ketoprofen -saccharide conjugates in organic media, Bioorg. Med. Chem. , 2009 , 17 , 1905-1910.
(20). Xiang, Y.-Z., Wang, N., Zhang, J., Li, K., Zhang, Z.-W., Lin, H.-H.*, Yu, X.-Q.* , Novel Cyclen-Based Linear Polymer as a High-Affinity Binding Material for DNA Condensation, SCI China B , 2009 , 52 , 483-488.
(21). Xiang, Y.-Z., Zhou, L.-H., Jiang, N., Lin, H.-H.*, Yu, X.-Q.* , Synthesis of a novel linear polymer of macrocyclic polyamine copper (II) complex and its interaction with plasmid DNA, J. Enzyme Inhibition Med. Chem ., 2009 , 24, 315-319.
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(23). Li , K. , Wang , N . , Yang , F . , Zhang , Z . -W . , Zhou , L . -H . , Chen , S . -Y . , Lin , H . -H .* , Tian , Y . -F . , Yu , X . -Q . * , Cyclen- b ased side-chain homop olymer self-assembly with plasmid DNA : Protect ion of DNA from enzymatic degradation , Chem. Biodivers., 200 9 , 6 , 754-763 .
(24). Li, K., Zhou, L.-H., Zhang, J., Chen, S.-Y., Zhang, Z.-W., Zhang, J.-J., Lin, H.-H.*, Yu, X.-Q.* , “Self-activating” Chemical Nuclease: Ferrocenyl Cyclen Cu( II ) Complexes Act as Efficient DNA Cleavage Reagents in the Absence of Reductant, Eur. J. Med. Chem. , 2009 , 44 , 1768-1772.
(25). Yang, X.-B., Wang, L., Zhang, J., Zhang, Z.-W., Lin, H.-H.*, Zhou, L.-H., Yu, X.-Q.* , A New Schiff Base Copper (II) Complex Derived from Estrone and D-Glucosamine: Synthesis, Characterization and Its Interaction with DNA, J. Enzyme Inhibition Med. Chem. , 2009 , 23 , 125-130.
(26). Li, K., Zhang, J., Zhang, Z.-W., Xiang, Y.-Z., Lin, H.-H., Yu, X.-Q.* , Immobilization Cyclen Copper (II) on Merrifield Resin: Efficient Oxidative Cleavage of Plasmid DNA , J. Applied Polym. Sci. , 2009 , 111 , 2485-2492.
(27). Xiang, Y.-Z., Liao, Y.-L., Zhang, J.*, Zhang, D.-W., Chen, S.-Y., Lu, Q.-S., Zhang, Y., Lin, H.-H,*, Yu, X.-Q.* , Linear disulfide-containing low polymer as efficient DNA cleavage reagent , Bioorg. Med. Chem. Lett. , 2009 , 19 , 3458–3460.
(28). Wang, L., Zhang, J., Wang, N., Yang, X.-B., Wang, Q., Yu, X.-Q.* , Asymmetric Catalysis of Diels-Alder Cycloaddition of 2-Alkenoyl Pyridine with Cyclopentadiene by Binaphthol-Titanium Complex , Lett. Org. Chem., 2009 , 6, 392-396.
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(30). Qin, J., Zhang, J., Wu, B., Zheng, Z.-G., Yang, M., Yu, X.-Q.* , Efficient and Mild Protocol for the Synthesis of 4(3)-Substituted 3(4)-Nitro-1 H -pyrroles and 3-Substituted 4-Methyl-2-tosyl-1 H pyrroles from Nitroolefins and Tosylmethyl Isocyanide in Ionic Liquids , Chinese J. Chem. , 2009 , 27 , 1782 - 1788.
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(32). Chen, S.-Y., Zhang, J., Li, Y.-H., Wen, J., Bian, S.-Q., Yu, X.-Q. * , Cobalt-catalyzed homo-coupling of aryl and alkenyl bromide using atmospheric oxygen as oxidant, Tetrahedron Lett. , 2009 , 50 , 6795–6797.
(33). Feng, X.-W., Li, C., Wang, N.*, Li, K., Zhang, W.-W., Wang, Z., Yu, X.-Q.* , Lipase-catalysed decarboxylative aldol reaction and decarboxylative Knoevenagel reaction , Green Chem. , 2009 , 11 , 1933-1936.
(34). Yue, Y, Turlington, M., Yu, X.-Q.* , Pu, L.*, 3, 3' -Anisyl-Substituted BINOL, H4BINOL, and H8BINOL Ligands: Asymmetric Synthesis of Diverse Propargylic Alcohols and Their Ring-Closing Metathesis to Chiral Cycloalkenes, J. Org. Chem. , 2009 , 74 , 8681-8689.
(35). Wen, J., Zhang, J., Chen, S.-Y., Li, J., Yu, X.-Q.* , Iron-Mediated Direct Arylation of Unactivated Arenes, Angew. Chem. Int. Ed. , 2008 , 47 , 8897-8900.
(36). Zheng, Z.-G., Wen, J., Wang, N., Wu, B., Yu, X.-Q.* , N-Arylation of amines, amides, imides and sulfonamides with arylboroxines catalyzed by simple copper salt/EtOH system , Beilstein J. Org. Chem., 2008 , 4 , No. 40. doi:10.3762/bjo c.4.40.
( 37 ). Li, C., Feng , X . -W . , Wang , N . , Zhou , Y . -J ., Yu , X . -Q . * , Biocatalytic promiscuity: the first lipase-catalysed asymmetric aldol reaction, Green Chem. , 2008 , 10 , 616-618 .
(38). Yang, X.-B., Feng, J., Zhang, J., Wang, N., Wang, L., Liu, J.-L., Yu, X.-Q* , Highly Enantioselective Hetero-Diels ?- Alder Reaction of trans-1-Methoxy-2-methyl-3-trimethylsiloxybuta-1,3-diene with Aromatic and Aliphatic Aldehydes Catalyzed by 3-Substituted BINOL - Titanium Complex, Org. Lett. , 2008 , 10 , 1299-1302.
(39). Huang, Y., Lu, Q.-S., Zhang, J., Zhang, Z.-W., Zhang, Y., Chen, S.-Y., Li, K., Tan, X.-Y., Lin, H.-H.* , Yu, X.-Q. * , DNA cleavage by novel copper (II) complex and the role of b -cyclodextrin in promoting cleavage , Bioorg. Med. Chem. , 2008 , 16 , 1103-1110.
(40). Yang, X.-B., Feng, J., Zhang, J., Zhang, Z.-W., Lin, H.-H.* , Zhou, L.-H. , Yu, X.-Q. * , Synthesis, DNA binding and cleavage activities of the copper (II) complexes of estrogen-macrocyclic polyamine conjugates , Bioorg. Med. Chem. , 2008 , 16 , 3871-3877.
(41). Yang, F., Wang, L., Li, X., Shen, J., Wang, J., Yu, X.-Q.* , Improved Preparation of Nabumetone by Raney Ni Catalytic Hydrogenation , Lett. Org. Chem., 2008 , 5, 191-193.
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(43). Tao, L., Yue, Y., Zhang, J., Chen, S.-Y., Yu, X.-Q.* , A Mild and Efficeint Method for N -Arylnucleobase Synthesis via the Cross-Coupling Reactions of Nucleobases with Arylboronic Acids Catalyzed by Simple Copper Salts , Helv. Chim. Acta , 2008 , 91 , 1008-1014.
(44). Wang, G.-Q., Zhang, J., Luo, S.-Z., Wang, N., Wei, H.-Y., Wang, W.-J., Yang, Y.-Q., Liu, G.-P., Yu, X.-Q.* , Synthesis and Primary Biological Evaluation of 188 ReN-NEMPTDD , J. Radioanaly. Nucl. Chem. , 2008 , 277 , 365-369.
(45). Zhao, Y.-C., Zhang, J., Wang, N., Yu, H., Yang, X.-B., Chen, S.-Y., Yu, X.-Q.* , Enantioselective Synthesis of 2, 6-Disubstituted Dihydropyrone Derivatives Catalyzed by TiCl 4 /BINOL/RONa System, Lett. Org. Chem. , 2008 , 5 , 391-395.
(46). Li, J., Yue, Y., Zhang, J., Lu, Q.-S., Li, K., Huang, Y., Zhang, Z.-W., Lin, H.-H.*, Wang, N., Yu, X.-Q. *, “Arm” effects of mononuclear cyclen copper complexes on DNA cleavage , Transit. Metal Chem. , 2008 , 33 , 759-765.
(47). Li, K., Zhang, J., Zhang, J.-J., Zhang, Z.-W., Zhuang, Z.-J., Xiao, D., Lin, H.-H.*, Yu, X.-Q.* , Ferrocene-Bridging Dinuclear Cyclen Copper( II ) Complexes as High Efficient Artificial Nucleases: Design, Synthesis and Interaction with DNA , Applied Organometal. Chem. , 2008 , 22 , 243-248.
(48). Li, C., Wang, H.-Y. Wang, N., * Fang, Y.-G., Chen, X., Yu, X.-Q. * , Highly regioselective enzymatic synthesis of polymerizable derivatives of methyl shikimate, Bioorg. Med. Chem. Lett. , 2007 , 17 , 6687-6690.
(49). Wang, R ., Lu, X. X .*, Yu, X. Q . *, Shi, L ., Sun, Y ., Acid-catalyzed solvent-free synthesis of 2-arylbenzimidazoles under microwave irradiation, J. Mol. Catal. A-Chem . 2007 , 266 (1-2) , 198-201.
(50). Tao, K ., Yu, X. Q .* , Liu, Y ., Shi, G. Y ., Liu, S. G ., Hou, T. P .*, Cloning, expression, and purification of insecticidal protein Pr596 from locust pathogen Serratia marcescens HR-3, Current Microbiology , 2007 , 55 (3) , 228-233.
(51). Huang, J., Huang, Q.-D., Zhang, J., Zhou, L.-H., Li, Q.-L., Li, K., Jiang, N., Lin, H.-H.*, Wu, J., Yu, X.-Q.* , Dinuclear Zinc (II) Complexes of Macrocyclic Polyamine Ligands Containing an Imidazolium Bridge: Synthesis, Characterization, and Their Interaction with Plasmid DNA, Int. J. Mol. Sci. 2007 , 8 , 606-617.
(52). He, L., Yu, J., Zhang, J., Yu, X.-Q.* , a -Amidation of cyclic ethers catalyzed by simple copper salts and a mild and efficient preparation method for a , v -aminoalcohols, Org. Lett. , 2007 , 9 , 2277-2280.
(53). Wang, Q., Chen, X., Tao, L., Wang, L., Xiao, D., Yu, X.-Q.* , Pu, L.*, Enantioselective Fluorescent Recognition of Amino Alcohols by a Chiral Tetrahydroxyl 1, 1' -Binaphthyl Compound, J. Org. Chem. , 2007 , 72, 97-101.
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(55). Wang, Q., Chen, S.-Y., Yu, X.-Q.* , Pu, L.*, 1, 1' -Binaphthyl ligands with bulky 3, 3' -tertiaryalkyl substitutes for the asymmetric alkyne addition to aromatic aldehydes, Tetrahedron , 2007 , 63, 4422-4428 .
(56). Zhao, Y.-C., Zhang, J., Huang, Y., Wang, G.-Q., Yu, X,-Q.* , DNA cleavage promoted by 2, 9-dimethyl-4, 7-diazadecane-2, 9-dithiol (DMDD) derivatives, Bioorg. Med. Chem. Lett. , 2007 , 17 , 2745-2748.
(57). Tan, X.-Y., Zhang, J., Huang, Y., Zhang, Y., Zhou, L.-H., Jiang, L., Lin, H.-H.*, Wang, N., Xia, C.-Q., Yu, X.-Q.* , Synthesis and DNA cleavage activities of the zinc(II), copper(II) and cobalt(II) complexes of benzocrown ether-fuctionalized 1,4,7,10-tetraazacyclododecane, Chem. Biodivers. , 2007 , 4 (9), 2190-2197.
(58). Liu, P.-Y., Jiang, N., Zhang, J., Wei, X., Lin, H.-H.*, Yu, X.-Q.* , The oxidative damage of plasmid DNA by ascorbic acid derivatives in vitro: The first research on the relationship between the structure of ascorbic acid and the oxidative damage of plasmid DNA, Chem. Biodivers. 2006 , 958-966.
(59). Gao, G., Wang, Q., Yu, X.-Q.* , Xie, R.-G., Pu, L.*, Highly Enantioselective Synthesis of g -Hydroxy- a , b -acetylenic Esters by Asymmetric AlkyneAddition to Aldehydes, Angew. Chem. Int. Ed. 2006 , 45 , 122-125.
(60). Zhao, Y.-C., Xiang, Y.-Z., Pu, L., Yang, M., Yu, X.-Q.* , Highly ? b ? - Selective Epoxidation of the D 5 - and D 4 -Unsaturated Steroids Catalyzed by the Silica-Supported Polyhalogenated Ruthenium Porphyrin , Applied Catal. A: General , 2006 , 301 , 176-181.
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(62). Xia, C.-Q., Jiang, N., Zhang, J., Chen, S.-Y., Lin, H.-H.*, Tan, X.-Y., Yue, Y., Yu, X.-Q.* , The Conjugates of Uracil-Cyclen Zn (II) Complexes: Synthesis, Characterization and Their Interaction with Plasmid DNA , Bioorg. Med. Chem. , 2006 , 14 , 5756-5764.
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獲獎記錄
1）. 四川省科技進步三等獎，生物功能體系的分子模擬，2001年7月。
2）. 2000 年校級優秀教學成果二等獎，理科大學生實踐能力培養研究 ------ 基礎有機化學實驗的課程體系改革研究，2000年12月
3）. 四川省科技進步二等獎，金屬膠束模擬水解金屬酶的研究，2006年7月
4）. 教育部高等學校科學研究優秀成果獎自然科學一等獎，簡單金屬鹽催化的C-C鍵和C-N鍵形成反應，2010年11月
5）. 四川省科技進步二等獎，天然藥物有效成分分離、類似物合成及藥效和臨床套用研究，2012年8月
6）. 四川大學教學成果獎一等獎，化學類本科創新能力培養的研究與實踐，2012年9月
7). 四川省教學成果一等獎，基於科研引導的研究型大學化學本科創新人才培養體系與實踐，2013年12月
2000 年：四川省做出突出貢獻的博士學位獲得者。
2003 年：入選四川省傑出青年學科帶頭人培養計畫。
2003 年：入選教育部新世紀優秀人才資助計畫。
2006 年：四川省學術和技術帶頭人。
2006 年：享受國務院政府特殊津貼專家。
2007 年：國家傑出青年基金獲得者。
2009 年：入選國家七部委新世紀百千萬人才工程國家級人選。
2009 年：教育部長江學者特聘教授。
