過渡金屬簇化學的最新進展

《過渡金屬簇化學的最新進展》是2000年05月科學出版社出版的圖書，作者盧嘉錫。本書介紹由盧嘉錫領導的中國科學院福建物質結構研究所實驗室20多年來取得的科研成果。

基本介紹

• 書名：過渡金屬簇化學的最新進展
• 作者：盧嘉錫
• 定價：298.00 元
• 出版社：科學出版社
• 出版時間： 2000年05月

基本信息

ISBN： 7-03-007788-1/O·1152 開本： 16 開

類別： 無機化學化工,物理化學 頁數： 485 頁

目錄

CHAPTERIIntroduction

LiuChunWan

11TheHistoricalBackgroundofClusterChemistry

12ThePresentSituationofMetalClusterChemistry

13From"UnitConstructionHypothesis"to"UnitConstructionTheory"

14AromaticityandQuasiAromaticity

15NewAspectsofSyntheticChemistryofTransitionMetalCluster

CompoundsReferencesCHAPTER2SurveyofStructuralRulesandTheoreticalRationalization

ChenZhi'Da

21Introduction

22StructuralTrendofTransitionMetalClusters

23GeneralSurveyofStructuralRules

24TheoreticalRationalizationfortheStructuralRules

References

CHAPTER3UnitConstructionTheoryofMetalClusterCompounds

ZhuangBotao,WuXinTao,ChenWen'Dan,HuangJinShun,LiuChun'Wan

andLuJiaXi

31A"UnitConstructionApproach"totheRationalSynthesesofTransition

MetalCubaneLikeClustersbytheUseofReactiveFragmentsasBuild

ingBlocks

32DesignedSynthesisforSomeTransitionMetalClustersInvolving

BridgingSuitidoLigands

33SynthesisofMetalClustersfromReactiveFragments

34TheReactivityTheoryofUnitConstructions

References

CHAPTER4ANewTypeofAromaticity

HuangJianQuan,ChengWenDon,ChenZhi'Da,LiJun,LiuChun'Wanand

LuJiaXi

4IExperimentalEvidencesofQuasiAromalicityintheMo(8)3Ring

42TheBondingModelandtheBondingPropertiesofClusterCores

M3(X)3(M=Mo,W;X0,S,CI,Br)

43LocalizedMolecularOrbitalStudiesontheQuasiAromaticity

44AhInitioStudiesonQuasiAromaticity

References

CHAPTER5BondingPropertiesoftheMM'XTransitionMetalClusterCompounds

LiuChunWanandChengWenDan

51Introduction

52BondingPropertiesoftheMoFe~SclusterCompounds

53BondingCharacteristicsoftheEarlyTransitionMetalCluster

Compounds

54StructuralRulesoftheTransitionMetalClusters