趙佳，浙江工業大學化學工程學院研究員、博士/碩士生導師，浙江省重點研發計畫項目首席科學家。入選2018年浙江工業大學“青年英才支持計畫”及2022年“十四五”高層次人才培育專項計畫。
長期從事綠色催化轉化與氯循環催化劑技術研究，結合原位表征技術與理論計算，聚焦多相金屬離子催化劑活性中心化學微環境構建策略，在工業催化劑穩定性提升和多尺度工程設計方面取得突破。主持國家重點研發計畫子課題、國家自然科學基金面上項目、“領雁”研發攻關計畫等國家級及省部級項目10餘項，承擔多項重大企業橫向項目。以第一作者/通訊作者在《Nature Communications》《ACS Catalysis》等期刊發表SCI論文50餘篇，含ESI熱點論文1篇、高被引論文8篇；獲授權中國發明專利49項，申請專利70餘項。研究成果套用於氯鹼、氟化工、能源等領域，參與構建的Cu-O-P耦合位點催化劑實現高效合成氯乙烯，累計完成18000小時工業側線測試。
基本介紹
人物經歷,研究方向,科研項目,科研成果,
人物經歷
趙佳，研究員，博士/碩士生導師，浙江省重點研發計畫項目首席科學家。入選2018年浙江工業大學“青年英才支持計畫”以及2022年浙江工業大學“十四五”高層次人才培育專項計畫。主持國家重點研發計畫項目子課題、浙江省科技計畫項目“領雁”研發攻關計畫、國家自然科學基金面上項目等國家級/省部級科研項目，以及多項重大企業橫向項目。以第一作者/通訊作者在Nature Communications，ACS Catalysis，Applied Catalysis B: Environmental，Journal of Catalysis，Chemical Engineering Journal等期刊上發表SCI論文50餘篇，其中ESI熱點論文1篇、ESI高被引論文8篇。申請中國發明專利70餘項，授權49項。
研究方向
緊扣我國氯鹼產業、氟化工、醫/農藥、能源產業等氯資源密集套用領域的國家重大需求，長期聚焦“創製綠色催化轉化與氯循環的催化劑技術”這一國際前沿科學難題的研究，注重以活性中心多尺度構築、過程機理揭示和產物選擇性調控為核心，結合原位表征技術與理論計算，提出了基於離域反應機理的多相金屬離子催化劑活性中心化學微環境構建策略，在工業催化劑長周期穩定性增強技術、以及多尺度催化劑工程設計與構建方面取得了研究突破。
科研項目
1. 國家自然科學基金委員會，面上項目，22472149，亞穩相Fe-B基納米晶合金催化劑非平衡金屬態表面電子態調控及催化Deacon反應性能研究，50萬元，在研，主持
2. 科學技術部，國家重點研發計畫項目子課題，2021YFA1501801，金屬活性中心的多尺度構築與可控制備，200萬元，在研，主持；
3. 科學技術部，國家重點研發計畫項目子課題，2021YFA1501802，催化反應機制和再生製備的技術基礎研究，103萬元，在研，主持
4. 浙江省科技廳，“尖兵”“領雁”研發攻關計畫項目，2023C01211，乙烯產業關鍵單體用高性能催化劑的研發與套用，250萬元，在研，主持
5. 國家自然科學基金委員會，青年基金項目，21606199，配位離子液體穩定金離子價的調控力及其機制研究，20萬元，已結題，主持
6. 浙江省科技計畫項目-公益技術，LGG20B060004，基於電中性配位機理構建升華型催化劑活性組分的穩定機制研究，10萬元，已結題，主持
7. 國家自然科學基金委員會，聯合基金重點項目，U20A20119，金屬@碳封裝催化劑體系的活性位形成及活性增強機制研究，280萬元，在研，參與
8. 國家自然科學基金委員會，面上項目，21476207，含氮碳材料雙鹼性位於催化脫氯化氫合成偏二氯乙烯性能研究，100萬元，已結題，參與
9. 國家自然科學基金委員會，青年基金項目，21506138，介孔碳材料中氮碳原子比與堆積形態的調控及催化性能研究，25萬元，已結題，參與
科研成果
學術論文
[1] Luyao Guo, Kaixuan Zhuge, Siyang Yan, Shiyi Wang, Jia Zhao*, Saisai Wang, Panzhe Qiao, Jiaxu Liu*, Xiaoling Mou, Hejun Zhu*, Ziang Zhao, Li Yan, Ronghe Lin*, Yunjie Ding*, Defect-driven nanostructuring of low-nuclearity Pt-Mo ensembles for continuous gas-phase formic acid dehydrogenation, Nature Communications, 2023, 14:7518-7529
[2] Yuxue Yue, Saisai Wang, Qi Zhou, Bolin Wang, Chunxiao Jin, Renqin Chang, Liqi Wan, Zhiyan Pan, Yihan Zhu, Jia Zhao*, Xiaonian Li*, Tailoring Asymmetric Cu-O-P Coupling Site by Carbothermal Shock Method for Efficient Vinyl Chloride Synthesis over Carbon Supported Cu Catalysts, ACS Catalysis, 2023, 13: 9777-9791.
[3] Saisai Wang, Liqi Wan, Chunxiao Jin, Tao Wang, Kaixuan Zhuge, Yuxue Yue, Haiting Cai, Bolin Wang, Renqin Chang, Jia Zhao*, Xiaonian Li, Mechanistic insight into acetylene hydrochlorination with Ru-ligands via dual activation promoted by metal-ligands cooperative catalysis, Applied Catalysis A: General, 2023, 665: 119382-119391.
[4] Feng Feng, Chunxiao Jin, Saisai Wang, Yuxue Yue, Da Xu, Kaixuan Zhuge, Pan Gao, Jia Zhao, Renqin Chang, Lingling Guo, Huaqing Dong*, Self-oxidation of Au-[Bmim][Cl3] catalyst with enhanced activity and stability for acetylene hydrochlorination, Applied Catalysis A: General, 2023, 661: 119238-119248.
[5] Huijun Song, Xiaoqiu Xu, Jingjing Chen, Yinling Zhang, Jia Zhao, Chongzhi Zhu, Hong Zhang, Yong Peng, Qiaoli Chen, Guan Sheng, Tulai Sun, Yu Han, Xiaonian Li, Yihan Zhu*, Evoking Cooperative Geometric and Electronic Interactions at Nanometer Coherent Interfaces toward Enhanced Electrocatalysis, Advanced Functional Materials: 2023, 33: 2301490-2301503.
[6] Zilong Zhang, Haifeng Zhang*, Bolin Wang*, Yuxue Yue, Jia Zhao*, Migration: A Neglected Potential Contribution of HCl-Oxidized Au(0). Molecules, 2023, 28: 1600. https://doi.org/10.3390/molecules28041600.
[7] Rongrong Li, Yuxue Yue, Yongkun Li, Xianlang Chen, Renqin Chang, Jiaxin Zhang, Bo Zhao, Xia Ying, Zijian Wang, Jia Zhao*, Xiaonian Li, Controlling the speciation and selectivity of Si3N4 supported palladium nanostructures for catalysed acetylene selective hydrogenation, Inorganic Chemistry Frontiers: 2022, 9, 5969-5982.
[8] Rongrong Li, Yuxue Yue, Xianlang Chen, Renqin Chang, Jiaxin Zhang, Bo Zhao, Jieyu Zhang, Di Cai, Yihan Zhu, Deman Han, Jia Zhao*, Xiaonian Li, Graphdiyne anchoring to construct highly dense palladium trimer active sites for the selective hydrogenation of acetylene, Nano Research, 2022, 16: 6167-6178.
[9] Zhongting Hu, Wenhao Xing, Siyan Gong, Tulai Sun, Cheng Wang, Mian Hu, Jia Zhao*, Zhiyan Pan, Wei Chen*, Zhong Chen, Xiaonian Li. Flower-like ZnIn2S4 microspheres with highly efficient catalytic activity for visible-light-driven sulfamethoxazole photodegradation. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022, 643: 128779-128788.
[10] Bolin Wang, Haifeng Zhang*, Yuxue Yue, Changlin Li, Jia Zhao*, Catalytic Behavior of Au Confined in Ionic Liquid Film: A Kinetics Study for the Hydrochlorination of Acetylene, Catalysts, 2022, 12: 1012-1021.
[11] Bolin Wang, Chunxiao Jin, Shujuan Shao, Yuxue Yue, Yuteng Zhang, Saisai Wang, Renqin Chang, Haifeng Zhang*, Jia Zhao*, Xiaonian Li*. Electron-deficient Cu site catalyzed acetylene hydrochlorination. Green Energy & Environment, 2022. 8: 1128-1140.
[12] Ting Wang, Zhao Jiang, Qi Tang, Bolin Wang, Saisai Wang, Mingde Yu, Renqin Chang, Yuxue Yue, Jia Zhao*, Xiaonian Li*. Interactions between atomically dispersed copper and phosphorous species are key for the hydrochlorination of acetylene. Communications Chemistry, 2022. https://doi.org/10.1038/s42004-021-00619-7.
[13] Mengru Wang, Yuxue Yue, Yi Wang, Xiaoling Mou, Renqin Chang, Zupeng Chen, Ronghe Lin*, Jia Zhao*, Yunjie Ding*. Selective hydrogenation of 1,3-butadiene on iridium nanostructures: Structure sensitivity, host effect, and deactivation mechanism. Journal of Energy Chemistry, 2022, 69: 541-554.
[14] Qi Tang, Yuxue Yue, Zhao Jiang, Feibiao Li, Ting Wang, Chunxiao Jin, Huaqing Dong*, Renqin Chang, Bolin Wang, Haiting Cai, Jia Zhao*, Xiaonian Li. Non-metallic carbon-based catalysts for acetylene hydrochlorination: The effect of graphitization degree of carbonaceous material. Catalysis Communications, 2022, 167: 106458-106463.
[15] Zhongting Hu, Yin Ding, Yuchao Shao, Luxiang Cai, Ziyan Jin, Zifeng Liu, Jia Zhao, Feili Li*, Zhiyan Pan, Xiaonian Li, Jun Zhao*. Banana peel biochar with nanoflake-assembled structure for cross contamination treatment in water: Interaction behaviors between lead and tetracycline. Chemical Engineering Journal, 2021, 420: 129807.
[16] Bolin Wang, Zhao Jiang, Ting Wang, Qi Tang, Mingde Yu, Tao Feng, Min Tian, Renqin Chang, Yuxue Yue, Zhiyan Pan, Jia Zhao*, Xiaonian Li*. Controllable Synthesis of Vacancy-Defect Cu Site and Its Catalysis for the Manufacture of Vinyl Chloride Monomer. ACS Catalysis, 2021, 11: 11016-11028.
[17] Bolin Wang,Yuxue Yue, Xiangxue Pang, Mingde Yu, Ting Wang, Renqin Chang, Zhiyan Pan, Jia Zhao*, Xiaonian Li. Nature of HCl oxidation Au anomalies and activation of non-carbon-material-supported Au catalyst. Journal of Catalysis, 2021, 404: 198-203.
[18] Jia Zhao*, Saisai Wang, Bolin Wang, Yuxue Yue, Jinyue Lu, Jinyue Lu, Zheng Fang, Xiangxue Pang, Feng Feng, Lingling Guo, Zhiyan Pan, Xiaonian Li. Acetylene hydrochlorination over suppopported ionic liquid phase(SILP) gold-based catalyst: stabilization of cationic Au species via chemical activation of hydrogen chloride and corresponding mechanisms. Chinese Journal of Catalysis, 2021, 42(2): 334-346.
[19] Bolin Wang, Yuxue Yue, Xiangxue Pang, Wenrui Zhu, Zhi Chen, Shujuan Shao, Ting Wang, Zhiyan Pan, Xiaonian Li, Jia Zhao*. Synergistic effect of two action sites on a nitrogen-doped carbon catalyst towards acetylene hydrochlorination. Physical Chemistry Chemical Physics, 2020, 22, 20995-20999.
[20] Bolin Wang, Yuxue Yue, Saisai Wang, Shujuan Shao, Zhi Chen, Xianhua Fang, Xiangxue Pang, Zhiyan Pan, Jia Zhao*, Xiaonian Li. Stabilizing supported gold catalysts in acetylene hydrochlorination by constructing an acetylene-deficient reaction phase. Green Energy & Environment, 2020.(Doi:10.1016/j.gee.2020.06.012)
[21] Bolin Wang, Yuxue Yue, Chunxiao Jin, Jinyue Lu, Saisai Wang, Lu Yu, Lingling Guo, Rongrong Li, Zhong-Ting Hu, Zhiyan Pan, Jia Zhao*, Xiaonian Li. Hydrochlorination of acetylene on single-atom Pd/N-doped carbon catalysts: Importance of pyridinic-N synergism. Applied Catalysis B: Environmental, 2020, 272, 118944-118954.
[22] Rongrong Li, Yuxue Yue, Zhi Chen, Xianlang Chen, Saisai Wang, Zhao Jiang, Bolin Wang, Qianqian Xu, Deman Han, Jia Zhao*. Selective hydrogenation of acetylene over Pd-Sn catalyst: Identification of Pd2Sn intermetallic alloy and crystal plane-dependent performance. Applied Catalysis B: Environmental, 2020, 279, 119348-119358.
[23] Bolin Wang, Yuxue Yue, Saisai Wang, Zhi Chen, Lu Yu, Shujuan Shao, Guojun Lan, Zhiyan Pan, Jia Zhao*, Xiaonian Li. Constructing and controlling ruthenium active phases for acetylene hydrochlorination. Chemical Communications, 2020, 56, 10722-10725.
[24] Yaqing Cen, Yuxue Yue, Saisai Wang, Jinyue Lu, Bolin Wang, Chunxiao Jin, Lingling Guo, Zhongting Hu, Jia Zhao*. Adsorption behaivor and electron structure engineering of Pd-based catalysts for acetylene hydrochlorination. catalysts, 2020, 10(1): 24-37.
[25] Yuxue Yue, Bolin Wang, Saisai Wang, Chunxiao Jin, Jinyue Lu, Zheng Fang, Shujuan Shao, Zhiyan Pan, Jun Ni, Jia Zhao*, Xiaonian Li. Boron-doped carbon nanodots dispersed on graphitic carbon as high-performance catalysts for acetylene hydrochlorination. Chemical Communications, 2020, 56, 5174-5177.
[26] Yi Yu, Yuxue Yue, Bolin Wang, Haihua He, Zhong-Ting Hu, Jia Zhao*, Xiaonian Li. Synergy between ionic liquids and CuCl2 in gas–liquid phase reactions of acetylene hydrochlorination. Catalysts, 2019, 9(6): 504-525.
[27] Haihua He, Jia Zhao*, Bolin Wang, Yuxue Yue, Gangfeng Sheng, Qingtao Wang, Lu Yu, Zhong-Ting Hu, Xiaonian Li. Highly active AuCu-based catalysts for acetylene hydrochlorination prepared using organic aqua regia. Materials, 2019, 12(8): 1310-1323.
[28] Yuxue Yue, Bolin Wang, Gangfeng Sheng, Huixia Lai, Saisai Wang, Zhi Chen, Zhong-Ting Hu, Jia Zhao*, Xiaonian Li. An ultra-high H2S-resistant gold-based imidazolium ionic liquid catalyst for acetylene hydrochlorination. New Journal of Chemistry, 2019, 43, 12767-12775.
[29] Jia Zhao*, Bolin Wang, Yuxue Yue, Gangfeng Sheng, Huixia Lai, Saisai Wang, Lu Yu, Qunfeng Zhang, Feng Feng, Zhong-Ting Hu, Xiaonian Li. Nitrogen- and phosphorus-codoped carbon-based catalyst for acetylene hydrochlorination. Journal of Catalysis, 2019, 373: 240-249.
[30] Huixia Lai, Bolin Wang, Yuxue Yue, Gangfeng Sheng, Saisai Wang, Feng Feng, Qunfeng Zhang, Jia Zhao*, Xiaonian Li. An Alternative Carbon Carrier in Green Preparation of Efficient Gold/Carbon Catalyst for Acetylene Hydrochlorination. ChemCatChem, 2019, 11(14): 3318-3326.
[31] Haihua He, Jia Zhao*, Bolin Wang, Yuxue Yue, Gangfeng Sheng, Qingtao Wang, Lu Yu, Zhong-Ting Hu, Xiaonian Li. Design strategies for the development of a Pd-based acetylene hydrochlorination catalyst: improvement of catalyst stability by nitrogen-containing ligands. RSC Advances, 2019, 9, 21557-21563.
[32] Jia Zhao*, Yuxue Yue, Gangfeng Sheng, Bolin Wang, Huixia Lai, Shuxia Di, Yuanyuan Zhai, Lingling Guo, Xiaonian Li*. Supported ionic liquid-palladium catalyst for the highly effective hydrochlorination of acetylene, Chemical Engineering Journal, 2019, 360, 38-46.
[33] Bolin Wang, Jia Zhao*, Yuxue Yue, Gangfeng Sheng, Huixia Lai, Jiayao Rui, Haihua He, Zhongting Hu, Feng Feng, Qunfeng Zhang, Lingling Guo, Xiaonian Li*. Carbon with Surface-Enriched Nitrogen and Sulfur Supported Au Catalysts for Acetylene Hydrochlorination, ChemCatChem, 2019, 11, 1002-1009.
[34] Bolin Wang, Huixia Lai, Yuxue Yue, Gangfeng Sheng, Yaqin Deng, Haihua He, Lingling Guo, Jia Zhao*, Xiaonian Li*. Zeolite Supported Ionic Liquid Catalysts for the Hydrochlorination of Acetylene, Catalysts, 2018, 8, 351-363.
[35] Shuxia Di, Yiqi Xu, Qunfeng Zhang, Xiaolong Xu, Yuanyuan Zhai, Bolin Wang, Haihua He, Qingtao Wang, Hao Xu, Yishu Jiang, Jia Zhao, Xiaonian Li. Insight into the dispersion behavior of 1-butyl-3-methylimiazolium chloride confined in nanoscale pores of carbon materials. RSC Advances, 2018, 8(43): 24094-24100.
[36] Jia Zhao*, Bolin Wang, Yuxue Yue, Shuxia Di, Yuanyuan Zhai, Haihua He, Gangfeng Sheng, Huixia Lai, Yihan Zhu, Lingling Guo, Xiaonian Li*. Towards a greener approach for the preparation of highly active gold/carbon catalyst for the hydrochlorination of ethyne, Journal of Catalysis, 2018, 365, 153-162.
[37] Yuanyuan Zhai, Jia Zhao*, Xiaoxia Di, Shuxia Di, Bolin Wang, Yuxue Yue, Gangfeng Sheng, Huixia Lai, Lingling Guo, Hong Wang and Xiaonian Li*. Carbon-supported perovskite-like CsCuCl3 nanoparticles: a highly active and cost-effective heterogeneous catalyst for the hydrochlorination of acetylene to vinyl chloride. Catal. Sci. Technol., 2018, 8, 2901-2908.
[38] Jia Zhao*, Bolin Wang, Xiaolong Xu, Yi Yu, Shuxia Di, Hao Xu, Yuanyuan Zhai, Haihua He, Lingling Guo, Zhiyan Pan, Xiaonian Li*. Alternative solvent to aqua regia to activate Au/AC catalysts for the hydrochlorination of acetylene, Journal of Catalysis, 2017, 350: 149-158.
[39] Jia Zhao*, Yi Yu, Xiaolong Xu, Shuxia Di, Bolin Wang, Hao Xu, Jun Ni, LingLing Guo, Zhiyan Pan, Xiaonian Li*. Stabilizing Au(III) in supported-ionic-liquid-phase (SILP) catalyst using CuCl2 via a redox mechanism. Applied Catalysis B: Environmental, 2017, 206: 175-183.
[40] Xiaolong Xu, Haihua He, Jia Zhao, Bailin Wang, Shanchuan Gu, Xiaonian Li. The ligand coordination approach for improving the stability of low-mercury catalyst in the hydrochlorination of acetylene. Chinese Journal of Chemical Engineering, 2017, 25(9): 1217-1221.
[41] Rongrong Li, Jia Zhao, Deman Han, Xiaonian Li. One-step synthesis of B-doped mesoporous carbon as supports of Pd nanoparticles for liquid phase catalytic hydrodechlorination. Catalysis Communications, 2017, 97, 116-119.
[42] Xiaolong Xu, Jia Zhao, Chunshan Lu, Xiaoxia Di, Shanchuan Gu, Xiaonian Li. Improvement of the stability of Hg/AC catalysts by CsCl for the high-temperature hydrochlorination of acetylene. Chinese Chemical Letters, 2016, 27(6): 822-826.
[43] Jia Zhao, Shanchuan Gu, Xiaolong Xu, Tongtong Zhang, Yi Yu, Xiaoxia Di, Jun Ni, Zhiyan Pan and Xiaonian Li*. Supported ionic-liquid-phase-stabilized Au(III) catalyst for acetylene hydrochlorination. Catalysis Science & Technology, 2016, 6, 3263-3270.
[44] Tongtong Zhang, Jia Zhao, Jiangtao Xu, Jinhui Xu, Xiaoxia Di, Xiaonian Li*. Oxygen and Nitrogen-doped Metal-free Carbon Catalysts for Hydrochlorination of Acetylene. Chinese Journal of Chemical Engineering, 2016, 34, 484-490.
[45] Xiao-Xia Di, Jia Zhao, Yi Yu, Xiao-Long Xu, Shan-Chuan Gu, HaiHua He, Tong-Tong Zhang, Xiao-Nian Li*. One-pot synthesis of nitrogen and sulfur co-doped activated carbon supported AuCl3 as efficient catalysts for acetylene hydrochlorination. Chinese Chemical Letters, 2016, 27, 1567-1571.
[46] Jun Ni, Jia Zhao, Luwei Chen, Jianyi Lin, Sibudjing Kawi. Lewis Acid Sites Stabilized Nickel Catalysts for Dry (CO2) Reforming of Methane. ChemCatChem, 2016, 8(24):3732-3739.
[47] Jia Zhao, Tongtong Zhang, Xiaoxia Di, Jiangtao Xu, Shanchuan Gu, Qunfeng Zhang*, Jun Ni and Xiaonian Li*. Activated carbon supported ternary gold-cesium(I)-indium(III) catalyst for the hydrochlorination of acetylene. Catalysis Science & Technology, 2015, 5, 4973-4984.
[48] Jia Zhao, Shanchuan Gu, Xiaolong Xu, Tongtong Zhang, Xiaoxia Di, Zhiyan Pan and Xiaonian Li*. Promotional effect of copper(II) on an activated carbon supported low content bimetallic gold-cesium(I) catalyst in acetylene hydrochlorination. RSC Advances, 2015, 5, 101427-101436.
[49] Jia Zhao, Jiangtao Xu, Jinhui Xu, Tongtong Zhang, Xiaoxia Di, Jun Ni, Xiaonian Li*. Enhancement of Au/AC acetylene hydrochlorination catalyst activity and stability via nitrogen-modified activated carbon support. Chemical Engineering Journal, 2015, 262, 1152-1160.
[50] Jia Zhao, Tongtong Zhang, Xiaoxia Di, Jiangtao Xu, Jinhui Xu, Feng Feng, Jun NI and Xiaonian Li*. Nitrogen-modified activated carbon supported bimetallic gold-cesium(I) as highly active and stable catalyst for the hydrochlorination of acetylene. RSC Advances, 2015, 5(9): 6925-6931.
[51] Jiangtao Xu, Jia Zhao, Tongtong Zhang, Xiaoxia Di, Shanchuan Gu, Jun Ni and Xiaonian Li*. Ultra-low Ru-promoted CuCl2 as highly active catalyst for the hydrochlorination of acetylene. RSC Advances, 2015, 5: 38159-38163.
[52] Jia Zhao, Jiangtao Xu, Jinhui Xu, Jun Ni, Tongtong Zhang, Xiaoliang Xu and Xiaonian Li*. Activated-Carbon-Supported Gold-Cesium(I) as Highly Effective Catalysts for Hydrochlorination of Acetylene to Vinyl Chloride. ChemPlusChem, 2014, 80(1): 196-201.
[53] Jinhui Xu, Jia Zhao, Jiangtao Xu, Tongtong Zhang, Xiaonian Li*, Xiaoxia Di, Jun Ni, Jianguo Wang* and Jie Cen. Influence of Surface Chemistry of Activated Carbon on the Activity of Gold/Activated Carbon Catalyst in Acetylene Hydrochlorination. Industrial & Engineering Chemistry Research, 2014, 53(37): 14272-14281.
[54] Jia Zhao, Xiaoliang Xu, Xiaonian Li* and Jianguo Wang*. Promotion of Sn on the Pd/AC catalyst for the selective hydrogenation of cinnamaldehyde. Catalysis Communications, 2014, 43: 102-106.
[55] Jia Zhao, Lei Ma, Xiaoliang Xu, Feng Feng and Xiaonian Li*. Synthesis of carbon-supported Pd/SnO2 catalyst for highly selective hydrogenation of 2,4-difluoronitrobenzene. Chinese Chemical Letters, 2014, 25: 1137-1140.
[56] Jia Zhao, Jun Ni, Jinhui Xu, Jiangtao Xu, Jie Cen and Xiaonian Li*. Ir promotion of TiO2 supported Au catalysts for selective hydrogenation of cinnamaldehyde. Catalysis Communications, 2014, 54, 72-76.
授權專利
(1) 李小年; 趙佳; 張群峰; 王柏林; 盧春山; 呂井輝; 一種離子液體促進的鈀基催化劑及其在催化不飽和烴氫化鹵化的套用, 2020-04-24, 中國, ZL201710906036.X.
(2) 李小年; 趙佳; 張桐桐; 谷山川; 許江濤; 一種多種固體材料負載型離子液體-金催化劑及其製備和套用, 2018-05-22, 中國, ZL201510452191.X.
(3) 李小年; 趙佳; 谷山川; 張桐桐; 張群峰; 盧春山; 豐楓; 一種炭負載金催化劑的製備方法及該催化劑的套用, 2017-09-29, 中國, ZL201510585673.2.
(4) 李小年; 趙佳; 張桐桐; 谷山川; 狄曉霞; 一種負載型三維鹵素橋接混合物金化合物催化劑及其製備和套用, 2017-06-23, 中國, ZL201510451183.3.
(5) 李小年; 趙佳; 張群峰; 豐楓; 岳玉學; 許孝良; 盧春山; 呂井輝; 馬磊;一種負載型硫化離子液體促進的釕催化劑及其在不飽和烴氫化鹵化中的套用, 2019-12-24, 中國, ZL201710907297.3.
(6) 李小年; 趙佳; 豐楓; 張桐桐; 許江濤; 狄曉霞; 張群峰; 盧春山; 馬磊;許孝良; 姚楠; 一種鈣鈦礦型複合氯化物催化劑及套用, 2017-09-29, 中國, ZL201510086239.X.
(7) 李小年; 趙佳; 谷山川; 張群峰; 豐楓; 盧春山; 呂井輝; 一種乙炔氣氛中高溫穩定的鈀複合物及其套用, 2020-04-24, 中國, ZL201710906153.6.
(8) 李小年; 趙佳; 張群峰; 豐楓; 楊倩; 鄧雅琴; 賴慧霞; 余禕; 一種用於乙炔氫氯化反應的釕配合物催化劑, 2020-06-09, 中國, ZL201710907290.1.
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