基本介紹
- 中文名：曹勇勇
- 畢業院校：浙江工業大學
- 學位/學歷：博士
- 職稱：副教授
人物經歷,研究方向,主要成就,獲獎記錄,
人物經歷
研究方向
主要從事單雙原子電催化氧還原反應（ORR）、氮還原反應（NRR）、二氧化碳還原反應（CO2RR）和尿素合成的實驗和理論研究。
主要成就
主持國家自然科學青年基金項目1項，浙江省一般項目1項，嘉興市精英.引領領軍人才項目1項，嘉興市公益基金項目1項，企業橫向項目4項；轉讓軟體著作權一項金額5萬元。以第一作者或通訊作者身份發表在J. Mater. Chem. A，Inorg. Chem，Chem. Commun，ACS Appl. Mater. Interfaces，J. Colloid. Inter. Sci, Green. Ener. Environ，Nanotechnology，Adv. Theor. Simu.等期刊發表論文30餘篇。指導本科生獲得國家級競賽三等獎4項，省級二等獎1項，省級三等獎3項。指導本科生獲得浙江省新苗項目1項，SRT項目兩項，指導本科生以第一作者發表SCI論文2篇。
主持項目:
1. 解質溶液局域環境下電催化合成雙氧水的理論模擬，國家青年基金項目，2022.01-2024.12.（主持人）；
2. 真實電解質溶液環境下電催化合成尿素的理論模擬，浙江省一般項目，2024.01-2026.12（主持人）；
3. 電催化雙氧水催化劑的智慧型設計和產品化，嘉興市公益項目，2023.01-2025.12（主持人）；
4. 高效雙氧水電催化劑的開發和規模化生產，嘉興市青年領軍項目，2022.01 -2025.12（主持人）；
5. 風機表面防腐關鍵技術套用，浙江犇通風機有限公司，2023.03-2025.03（主持人）；
6. 高效防火型裝配式牆體建築材料的設計及技術研發，2023.07-2024.04（主持人）；
7. 高附著力面料印花染料開發和設備技術改進研發及套用，2023.08-2024.08（主持人）。
代表論文（近五年）：
[1] Yongyong Cao, Yuxiao Meng, Yuting Wu, Hongjie Huang, Weichan Zhong, Zhangfeng Shen, Qineng Xia, Yangang Wang and Xi Li. Metal-free boron nanosheet as “buffer electron pool” for urea and ethanol synthesis via C–N and C–C coupling. J. Mater. Chem. A, 2022, 10, 23843-23853.
[2] Yuxiao Meng, Zhangmeng Xu, Zhangfeng Shen, Qineng Xia, Yongyong Cao*, Yangang Wang * and Xi Li*, Understanding the water molecule effect in metal-free B-based electrocatalysts for electrochemical CO2 reduction. J. Mater. Chem. A, 2022,10, 6508-6522.
[3] Yongyong Cao, Yuxiao Meng, Yuting Wu, Zhangfeng Shen, Qineng Xia, Hong Huang, Jian-Ping Lang, Hongwei Gu, Yangang Wang,* and Xi Li*, Regulation of the Coordination Structures of Transition Metals on Nitrogen-Doped Carbon Nanotubes for Electrochemical CO2 Reduction. Inorg. Chem. 2022, 61, 18957−18969
[4] Fucheng Wang, Yuxiao Meng, Xuanqi Chen, Lu Zhang, Guohua Li, Zhangfeng Shen, Yangang Wang*, Yongyong Cao*, Effect of Nickel-based Electrocatalyst size on Electrochemical Carbon Dioxide Reduction: A Density Functional Theory Study, 2022, J. Coll, Inter, Sci. 615, 587–596.
[5] Zhangxin Chen, Jiajie Cao, Xiaohui Wu, Dongqin Cai, Minghui Luo, Shuyu Xing, Xiuli Wen, Yongyin Chen, Yanxian Jin*, Dan Chen, Yongyong Cao*, Lingmin Wang, Xianqiang Xiong, and Binbin Yu*, B, N Co-Doping Sequence: An Efficient Electronic Modulation of thePd/MXene Interface with Enhanced Electrocatalytic Properties for Ethanol Electrooxidation, ACS Appl. Mater. Interfaces, 2022, 14, 12223−12233.
[6] Mengmeng Shao, Haodeng Chen, Yongyong Cao*, Shushu Fu, Shiji Hao, Min Chen, Jutao Jin, Wenlong Wang, Yunhui Wu and Lifeng Cui*, Phase transition in V-doped cobalt hydroxide for a superior alkaline hydrogen evolution reaction, Chem. Commun., 2022, 58, 12859
[7] Yongyong Cao, JinYan Zhao, Xing Zhong, Guilin Zhuang, Shengwei Deng, Zhongzhe Wei, Zihao Yao, Jianguo Wang*, Building highly active hybrid double–atom sites in C2N for enhanced electrocatalytic hydrogen peroxide synthesis, Green Ene. Envir, 2021, 6, 846–857.
[8] Yongyong Cao, Guobing Zhou, Xianlang Chen, Qi Qiao, Chenxia Zhao, Xiang Sun, Xing Zhong,Guilin Zhuang, Shengwei Deng, Zhongzhe Wei, Zihao Yao, Liangliang Huang* and Jianguo Wang*. Hydrogen Peroxide Synthesis on Porous Graphitic Carbon Nitride Using Water as Hydrogen Source. J. Mater. Chem. A, 2020, 8, 124-137.
[9] Yongyong Cao, Chenxia Zhao, Qiaojun Fang, Xing Zhong, Guilin Zhuang, Shengwei Deng, Zhongzhe Wei, Zihao Yao and Jianguo Wang*. Hydrogen Peroxide Electrochemical Synthesis on Hybrid Double-Atoms (Pd-Cu) doped N vacancy g-C3N4: A Novel Design Strategy for Electrocatalysts Screening. J. Mater. Chem. A, 2020, 8, 2672-2683.
[10] Yongyong Cao, Shengwei Deng*, Qiaojun Fang, Xiang Sun, ChenXia Zhao, Jingnan Zheng, Yijing Gao, Han Zhuo, Yuejin Li，Zihao Yao, Zhongzhe Wei, Xing Zhong, Guilin Zhuang and Jianguo Wang*. Single and double boron atoms doped nanoporous C2N−h2D electrocatalysts for highly efficient N2 reduction reaction: A density functional theory study. Nanotechnology, 2019, 30, 335403.
[11] Yongyong Cao, Zhao, JY, Zhong, X, Zhuang, GL, Deng, SW, Wei, ZZ, Yao, ZH, Wang, JG.* Building highly active hybrid double-atom sites in C2N for enhanced electrocatalytic hydrogen peroxide synthesis, GREEN ENERGY & ENVIRONMENT, 2021, 6(6), 846-857
[12] Yongyong Cao, Yijing Gao, Hu Zhou, Xianlang Chen, Hui Hu, Shengwei Deng, Xing Zhong, Guilin Zhuang and Jianguo Wang*. High Efficient Ammonia Synthesis Electrocatalyst: Single Ru Atom on Naturally Nanoporous Carbon Materials. Adv. Theory Simul. 2018, 1800018.
[13] 曹勇勇, 蔣軍輝, 倪哲明*, 夏盛傑, 錢夢丹, 薛繼龍. Au19Pt 團簇性質及對肉桂醛選擇性加氫機理研究. 高等學校化學學報，2016，7, 1342-1350.
[14] Meng, YX，Xu, ZM，Shen, ZF，Xia, QN，Yongyong Cao *，Wang, YG*，Li, X*.Understanding the water molecule effect in metal-free B-based electrocatalysts for electrochemical CO2 reduction[J], J. Mater. Chem. A, A, 2022,10(12), 6508-6522.
[15] Chen, ZX, Cao, JJ, Wu, XH, Cai, DQ, Luo, MH, Xing, SY, Wen, XL, Chen, YY, Jin, YX, Chen, D, Yongyong Cao *, Wang, LM, Xiong, XQ, Yu, BB. B, N Co-Doping Sequence: An Efficient Electronic Modulation of the Pd/MXene Interface with Enhanced Electrocatalytic Properties for Ethanol Electrooxidation[J], ACS APPLIED MATERIALS & INTERFACES, 14(4), 12223-12233
[16] Wang, FC; Meng, YX ; Chen, XQ; Zhang, L; Li, GH; Shen, ZF ; Wang, YG; Yongyong Cao *, Effect of nickel-based electrocatalyst size on electrochemical carbon dioxide reduction: A density functional theory study[J], JOURNAL OF COLLOID AND INTERFACE SCIENCE, 615, 587-596
[17] Qiaoqiao Zhang, Yongyong Cao(共同一作), Yilong Yan, Bowen Yuan, Haiyang Zheng, Yu Gu, Xing Zhong and Jianguo Wang*. Synergetic Effect of Pyrrolic-N and Doped Boron in Mesoporous Carbon for Electrocatalytic Ozone production. J. Mater. Chem. A, 2020, 8, 2336-2342.
[18] Ziying Yuan, Yongyong Cao*, Yue Meng, Guoxiang, Yifan Zheng , Zheming Ni, Shengjie Xia*. The construction of lattice-matched CdS-Ag2S heterojunction photocatalysts: High-intensity built-in electric field effectively boosts bulk-charge separation efficiency. J. Hazard. Mater. 2023, 458, 131895.
[19] Zhangxin Chen, Jiajie Cao, Xiaohui Wu, Dongqin Cai, Minghui Luo, Shuyu Xing, Xiuli Wen, Yongyin Chen, Yanxian Jin,* Dan Chen, Yongyong Cao*, Lingmin Wang, Xianqiang Xiong, and Binbin Yu*. B, N Co-Doping Sequence: An Efficient Electronic Modulation of the Pd/MXene Interface with Enhanced Electrocatalytic Properties for Ethanol Electrooxidation. ACS Appl. Mater. Interfaces. 2022, 14, 12223−12233.
[20] Qiaoqiao Zhang,‡ Yongyong Cao,‡ Yilong Yan, Bowen Yuan, Haiyang Zheng, Yu Gu, Xing Zhong* and Jianguo Wang*. Synergetic effect of pyrrolic-N and doped boron in mesoporous carbon for electrocatalytic ozone production. J. Mater. Chem. A. 2020, 5.
[21] Shaoda Huang, Shuanglong Lu*, Yiming Hu, Yongyong Cao*, Yang Li, Fang Duan, Han Zhu, Yinghua Jin, Mingliang Du* and Wei Zhang*. Covalent Organic Frameworks with Molecular Electronic Modulation as Metal-Free Electrocatalysts for Efficient Hydrogen Peroxide Production. Small Struct. 2023, 2200387.
[22] Mengmeng Shao*, Shushu Fu, Yongyong Cao*, Shiji Hao, Haifeng Dang, Min Chen, Jutao Jin, Wenlong Wang, Jiaxing Wang, Lina Zuo, Dexing Zhang, and Xiaoji Wang*. Phase-Engineered Robust Cocatalyst of NiFe Bicarbonate with Pt Dopant for Enhanced Photocatalytic Water Splitting. Chem Asian J. 2023, e202300263.
[23] Mengmeng Shao*, Haodeng Chen, Yongyong Cao*, Shushu Fu, Shiji Hao, Min Chen,a Jutao Jin, Wenlong Wang, Yunhui Wu and Lifeng Cui*. Phase transition in V-doped cobalt hydroxide for a superior alkaline hydrogen evolution reaction. Chem. Commun., 2022,58, 12859.
授權專利：
鐘興, 王建國, 曹勇勇. 一種基於氧化鉑合金負載硼,氮摻雜金剛石的催化劑及其製備方法和套用. 中國，CN 109112571 B，2019.10.01（授權）
本專利已經成功轉讓企業，轉讓金額高達1008萬元。
轉讓軟著：
單原子催化劑O2吸附自動建模及雙氧水過電勢機器學習預測集成系統 _V1.0 （5萬元）。
獲獎記錄
1. 獲IOP出版社旗下期刊本年度的“中國高被引文章獎”；
2. 獲浙江省優秀博士論文提名獎；
3. 獲2023年嘉興大學優秀黨員稱號；
4. 獲2023年嘉興大學優秀畢業論文指導老師稱號。
