柏嵩，男，博士，浙江師範大學副教授，碩士生導師。
基本介紹
- 中文名：柏嵩
- 畢業院校：中國科學技術大學
- 學位/學歷：博士
- 職業：教師
- 專業方向：無機化學
- 任職院校：浙江師範大學化學與生命科學學院
研究方向,學術成果,承擔項目,學術論文,學生培養,榮譽獎項,
研究方向
1.複合光催化劑的表界面設計用於太陽能驅動化學品的合成，如光解水產氫，光催化還原CO2等。
2.新型電催化劑和光電催化劑的可控合成用於催化析氫，CO2還原等清潔能源的開發。
學術成果
承擔項目
理研究國家自然科學基金青年基金2017.1–2019.12主持（在研）。
2.用於二氧化鈦轉化甲烷串聯反應的可見光回響Au-TiO2-Pd/NiO複合光催化劑的設計與合成研究浙江省自然科學基金青年基金2016.1–2018.12主持（擬結題）。
學術論文
目前發表第一/通訊作者論文50餘篇，包括Angew. Chem. Int. Ed.、Adv. Mater.、Chem. Soc. Rev.、Nano Energy、Adv. Sci.、Small、Nano Res.、Chem. Commun.、ACS Appl. Mater. Interfaces、J. Mater. Chem. A、ChemSusChem、Nanoscale、Applied Catal. B: Environ.、Carbon、Chem. Eng. J.等化學和材料領域的重要期刊。研究論文已被他人引用2600餘次，單篇最高他引400餘次，8篇論文入選ESI高引頻論文，1篇論文入選ESI熱點論文，h-index為25。
2019年
64.X. Cai, J. Wang, R. Wang, A. Wang, S. Zhong, J. Chen andS. Bai*,Interface engineering on Janus Pd-Au heterojunction co-catalysts for selective photocatalytic reduction of CO2to CH4.J. Mater. Chem. A,DOI:10.1039/C9TA00172G(2019 Journal of Materials Chemistry A HOT Papers).
63.J. Lu, Y. Chen, L. Li, X. Cai, S. Zhong*, L. Wu, J. Chen andS. Bai*,Facet engineering on the interface of BiOCl-PbSheterostructures for enhanced broad-spectrumphotocatalytic H2production.Chem. Eng. J.,2019, 362, 1–11.
62.S. Bai*, C. Gao, J. Low and Y. Xiong*,Crystal phase engineering on photocatalytic materials for energy and environmental applications.Nano Res.,DOI: 10.1007/s12274-018-2267-6.
61.J. H. Wu, F. Q. Shao, S. Y. Han,S. Bai, J. J. Feng, Z. Li and A. J. Wang*,Shape-controlled synthesis of well-dispersed platinum nanocubes supported on graphitic carbon nitride as advanced visible-light-driven catalyst for efficient photoreduction of hexavalent chromium.J. Colloid Interface Sci.,2019, 535, 41–49.
2018年
60.S. Bai*, N. Zhang, C. Gao and Y. Xiong*, Defect engineering in photocatalytic materials.Nano Energy, 2018, 53, 296–336.
59.X. Cai, A. Wang, J. Wang, R. Wang, S. Zhong, Y. Zhao, L. Wu, J. Chen andS. Bai*,Ordered engineering on the lattice of intermetallic PdCu co-catalysts in boosting the photocatalytic conversion of CO2into CH4.J. Mater. Chem. A,2018, 6, 17444–17456. (2018 Journal of Materials Chemistry A HOT Papers).
58.L. Zhao, F. Ye, D. Wang, X. Cai, C. Meng,H. Xie, J. Zhang andS. Bai*, Lattice engineering on metal cocatalysts for enhanced photocatalytic reduction of CO2into CH4.ChemSusChem, 2018, 11, 3524–3533.
57.F. Ye, F. Wang, C. Meng, L. Bai, J. Li, P. Xing, B. Teng,* L. Zhao* andS. Bai*,Crystalline phase engineering on cocatalysts: A promising approach to enhancement on photocatalytic conversion of carbon dioxide to fuels.Appl. Catal. B: Environ., 2018, 230, 145–153.
56.L. Bai, X. Cai, J. Lu, L. Li, S. Zhong,* L. Wu, P. Gong, J. Chen andS. Bai*, Surface and interface engineering in Ag2S@MoS2core-shell nanowire heterojunctions for enhanced visible photocatalytic hydrogen production.ChemCatChem, 2018, 10, 2107–2114.
55. Q. Yin, L. Tan, Q. Lang, X. Ke, L. Bai, K. Guo, R. Qiao*andS. Bai*,Plasmonic molybdenum oxide nanosheets supported silver nanocubes for enhanced near-infraredantibacterial activity: synergismof photothermal effect, silver release and photocatalytic reactions.Appl. Catal. B: Environ., 2018, 224, 671–680.
54.Q. Lang, Y. Chen, T. Huang, L. Yang, S. Zhong, L. Wu, J. Chen andS. Bai*, Graphene “bridge” in transferring hot electrons from plasmonic Ag nanocubes to TiO2nanosheets for enhanced visible light photocatalytic hydrogen evolution.Appl. Catal. B: Environ., 2018, 220, 182–190.
2017年
53.Q. Lang, W. Hu, P. Zhou, T. Huang, S. Zhong*, L. Yang, J. Chen andS. Bai*, Twin defects engineered Pd cocatalyst on C3N4nanosheets for enhanced photocatalytic performance in CO2reduction reaction.Nanotechnology,2017,28,484003(Invited research article, Focus on CO2reduction).
52.Z. Xu, Y. Zhu, L. Bai, Q. Lang, W. Hu, C. Gao, S. Zhong andS. Bai*,Chemicaletching of graphene supported PdPt alloy nanocubes into concave nanostructures for enhanced catalytic hydrogen production from alkaline formaldehyde aqueous solution.Inorg. Chem. Front., 2017,4,1704–1713.
51.L.Bai, F.Ye, L.Li, J.Lu, S.ZhongandS.Bai*,Facetengineeredinterfacedesign ofplasmonicmetal andcocatalyst on BiOClnanoplates forenhancedvisiblephotocatalyticoxygenevolution.Small, 2017, 13, 1701607.
50.Q. Lang, Y. Yang, Y. Zhu, W. Hu, W. Jiang, S. Zhong, P. Gong, B. Teng*, L. Zhao* andS. Bai*,High-index facet engineering on PtCu cocatalyst for superior photocatalytic reduction of CO2toCH4.J. Mater. Chem. A,2017,5, 6686–6694.
49. C. Cui,M. Tou, M. Li, Z. Luo, L. Xiao,S. Baiand Z. Li*,Heterogeneous semiconductor shells sequentially coated on upconversion nanoplates for NIR-light enhanced photocatalysis.Inorg. Chem., 2017, 56, 2328–2336.
48. Y. Zhu, C. Gao,S. Bai*, S. Chen, R. Long, L. Song, Z. Li* and Y. Xiong*, Hydriding Pd cocatalysts: an approach to giant enhancement on photocatalytic CO2reduction into CH4.Nano Res., 2017, 10, 3396–3406.
47. Y. Zhu, Z. Xu, Q. Lang, W. Jiang, Q. Yin, S. Zhong andS. Bai*, Grain boundary engineered metal nanowire cocatalysts for enhanced photocatalytic reduction of carbon dioxide.Appl. Catal. B: Environ., 2017, 206, 282–292.
46. Y. Zhu, Z. Xu, W. Jiang, S. Zhong, L. Zhao andS. Bai*,Engineering on the edge of Pd nanosheet cocatalysts for enhanced photocatalytic reduction of CO2to fuels.J. Mater. Chem. A,2017,5, 2619–2628.
45.S. Bai*, L. Wang, Z. Li and Y. Xiong*, Facet-engineered surface and interface design of photocatalytic materials.Adv. Sci., 2017,4,1600216 (入選ESI高引頻論文).
44.M. Tou, Z. Luo,S. Bai, F. Liu, Q. Chai, S. Li and Z. Li*,Sequential coating upconversion NaYF4:Yb,Tm nanocrystals with SiO2and ZnO layers for NIR-driven photocatalytic andantibacterial applications,Mater. Sci. Eng. C, 2017, 70, 1141–1148.
2016年
43. L. Bai, W. Jiang, C. Gao, S. Zhong, L. Zhao, Z. Li* andS. Bai*, Facet engineered interface design of NaYF4:Yb,Tm upconversion nanocrystals on BiOCl nanoplates for enhanced near-infrared photocatalysis.Nanoscale,2016,8, 19014–19024.
42. W. Yin, L. Bai, Y. Zhu, S. Zhong, L. Zhao, Z. Li* andS. Bai*, Embedding metal in the interface of p-n heterojunction with stack design for superior Z-scheme photocatalytic hydrogen evolution.ACS Appl. Mater. Interfaces, 2016, 8, 23133–23142.
41. K. Wang, W. Qincheng, F. Wang,S. Bai, S. Li and Z. Li*,Coating a N-doped TiO2shell on dually sensitized upconversion nanocrystals to provide NIR-enhanced photocatalysts for efficient utilization of upconverted emissions.Inorg. Chem. Front., 2016,3, 1190–1197.
40.S. Bai*, W. Yin, L. Wang, Z. Li and Y. Xiong*,Surface and interface design of cocatalysts for photocatalytic water splitting and CO2reduction.RSC Adv., 2016, 6, 57446–57463.
39.Y. Zhu,Z. Xu,W. Jiang,W. Yin,S. Zhong,P. Gong,R. Qiao,Z. Li*andS. Bai*,Ultrathin nanosheets of palladium in boosting its cocatalyst role and plasmonic effect towards enhanced photocatalytic hydrogen evolution.RSC Adv., 2016,6, 56800–56806.
38. W. Yin,S. Bai, Y. Zhong, Z. Li* and Y. Xie,Direct generation of fine Bi2WO6nanocrystals on g-C3N4nanosheets for enhanced photocatalytic activity.ChemNanoMat,2016, 2, 732–738.
37.S. Bai, M. Xie, Q. Kong, W. Jiang, R. Qiao, Z. Li*, J. Jiang* and Y. Xiong*.Incorporation of Pd into Pt co-catalysts toward enhanced photocatalytic water splitting.Part. Part. Syst. Charact.,2016,33, 506–511.
36. W. Jiang,S. Bai*, L. Wang, X. Wang, L. Yang, Y. Li, D. Liu, X. Wang, Z. Li, J. Jiang andY. Xiong*.Integration of multiple plasmonic and co-catalyst nanostructures on TiO2nanosheets for visible-near-infrared photocatalytic hydrogen evolution.Small,2016,12, 1640–1648(入選ESI高引頻論文) .
35.J. Feng, C. An*, L. Dai, J. Liu, G. Wei,S. Bai, J. Zhang*and Y. Xiong*.Long-term production of H2over Pt/CdS nanoplates under sunlight illumination.Chem. Eng. J.,2016, 283, 351–357.
34.L. Lei,S. Bai*, W. Yin, S. Li, Y. Zhang and Z. Li*. A novel etching and reconstruction route to ultrathin porous TiO2hollow spheres for enhanced photocatalytic hydrogen evolution.Int. J. Hydrogen Energy,2016, 41, 1627–1634.
33.M. Tou, Y. Mei,S. Bai*, Z. Luo, Y. Zhang and Z. Li*.Depositing CdS nanoclusters on carbon-modifiedNaYF4:Yb,Tm upconversion nanocrystals for NIR light enhanced photocatalysis.Nanoscale,2016,8, 553–562.
2015年
32. S. Bai, L. Yang, C. Wang, Y. Lin, J. Lu, J. Jiang and Y. Xiong*. Boosting photocatalytic water splitting: interfacial charge polarization in atomically controlled core-shell co-catalyst.Angew. Chem. Int. Ed., 2015, 54, 14810–14814 (VIP paper).
31.S. Bai, J. Jiang, Q. Zhang and Y. Xiong*. Steering charge kinetics in photocatalysis: intersection of materials syntheses, characterization techniques and theoretical simulations.Chem. Soc. Rev.,2015, 44, 2893–2939 (back cover)(入選ESI高引頻論文).
30.S. Bai, X. Li, Q. Kong, R. Long, C. Wang, J. Jiang and Y. Xiong*. Toward enhanced photocatalytic oxygen evolution: synergetic utilization of plasmonic effect and schottky junction via interfacing facet selection.Adv. Mater.,2015, 27, 3444–3452(入選ESI高引頻論文).
29.S. Zhou,S. Bai*,E. Cheng,R. Qiao,Y. XieandZ. Li*.Facile ‘embedding’ of Au nanocrystals into silica spheres with controllable quantity for improved catalytic reduction ofp-nitrophenol.Inorg. Chem. Front., 2015,2, 938–944.
28.S. Bai, C. Wang*, W. Jiang, N. Du, J. Li, J. Du, R. Long, Z. Li and Y. Xiong*. Etching approach to hybrid structures between PtPd nanocages and graphene towards efficient oxygen reduction reaction.Nano Res.,2015,8, 2789–2799.
27.S. Bai, L. Wang, X. Chen, J. Du and Y. Xiong*. Chemically exfoliated metallic MoS2nanosheets: a promising supporting co-catalyst for enhancing photocatalytic performance of TiO2nanocrystals.Nano Res.,2015, 8, 175–183(Top Papers Award of Nano Research in 2017,入選ESI高引頻論文).
26.S. Bai, and Y. Xiong*.Some recent developments in surface and interface design for photocatalytic and electrocatalytic hybrid structures.Chem. Commun.,2015, 51, 10261–10271.
25.S. Baiand Y. Xiong*. Recent advances in two-dimensional nanostructures for catalysis applications.Sci. Adv. Mater.,2015, 7, 2168–2181(入選ESI熱點論文).
24.S. Bai, W. Jiang, Z. Li and Y. Xiong*.Surface and interface engineering in photocatalysis.ChemNanoMat,2015,1, 223–239.
23.C. Wang*,S. Baiand Y. Xiong*, Recent Advances in Surface and Interface Engineering for Electrocatalysis.Chin. J. Catal., 2015, 36, 1476–1493.
22.S. Baiand Y. Xiong*.Precise control over the surface and interface structures of nanocatalysts.Sci. Adv. Today,2015,1, 25215.
21.E. Cheng, W. Yin,S. Bai, R. Qiao, Y. Zhong and Z. Li*,Synthesis of vis/NIR-driven hybrid photocatalysts by electrostatic assembly of NaYF4:Yb, Tm nanocrystals on g-C3N4nanosheets.Mater. Lett., 2015, 146, 87–90.
2014年
20. S. Bai, C. Wang, M. Deng, M. Gong, Y. Bai, J. Jiang and Y. Xiong*. Surface polarization matters: enhancing hydrogen evolution reaction by shrinking Pt shells in Pt-Pd-graphene stack structures. Angew. Chem. Int. Ed.,2014, 53, 12120–12124 (back cover, 入選ESI高引頻論文).
19. S. Bai, J. Ge, L. Wang, M. Gong, M. Deng, Q. Kong, L. Song, J. Jiang*, Q. Zhang*, Y. Luo, Y. Xie and Y. Xiong*. A unique semiconductor-metal-graphene stack design to harness charge flow for photocatalysis. Adv. Mater.,2014, 26, 5689–5695 (inside front cover).
18. S. Bai, X. Wang, C. Hu, M. Xie, J. Jiang*and Y. Xiong*.Two-dimensional g-C3N4: an ideal platform for examining facet selectivity of metal co-catalysts in photocatalysis. Chem. Commun.,2014, 50, 6094–6097 (inside front cover).
17. L. Wang, J. Ge, A. Wang, M. Deng, X. Wang,S. Bai, R. Li,J. Jiang*, Q. Zhang*, Y. Luo and Y. Xiong*. Designing p-Type semiconductor-metal hybrid structures for improved photocatalysis.Angew. Chem. Int. Ed.,2014, 53, 5107–5111.
16. R. Long, K. Mao, M. Gong, S. Zhou, J. Hu, M. Zhi, Y. You,S. Bai, J. Jiang, Q. Zhang*, X. Wu* and Y. Xiong*. Tunableoxygen activation for catalytic organic oxidation: schottky junction versusplasmonic effects. Angew. Chem. Int. Ed.,2014, 53, 3205–3209.
15.Z. Ji, X. Shen*, Y. Xu, H. Zhou,S. Baiand G. Zhu. A facile and general route for the synthesis of semiconductor quantum dots on reduced graphene oxide sheets. RSC Adv., 2012, 4, 13601–13609.
2013年
14.S. Bai,X. Shen*, G. Zhu, A. Yuan, J. Zhang, Z. Ji and D. Qiu.The influence of wrinkling in reduced graphene oxide on their adsorption and catalytic properties.Carbon,2013, 60, 157–168.
13.S.Bai,X.Shen*, H.Lv, G.Zhu,C. Bao and Y. Shan,Assembly of Ag3PO4nanocrystals on graphene-based nanosheets with enhanced photocatalytic performance.J. Colloid Interface Sci.,2013, 405, 1–9.
12.S.Bai, X.Shen*, G.Zhu, H.Zhou, H.Xu, G.FuandZ.Ye,Optical properties and a simple and general route for the rapid syntheses of reduced graphene oxide-metal sulfide nanocomposites.Eur. J. Inorg. Chem., 2013, 256–262.
11. C. Wang, L. Ma, L. Liao,S. Bai, R. Long, M. Zuoand Y. Xiong*. A unique platinum-graphene hybrid structure for highactivity and durability in oxygen reduction reaction.Sci. Rep., 2013,3, 2580.
2012年
10.S.Bai,S. Chen,X.Shen*, G.Zhu and G.Wang.Nanocomposites of hematite (α-Fe2O3) nanospindles with crumpledreduced graphene oxide nanosheets as high-performance anode materialfor lithium-ion batteries,RSC Adv., 2012,2, 10977–10984(入選ESI高引頻論文).
9.S.Bai, X.Shen*, G.Zhu, M.Li, H.Xi and K.Chen.In situ growth of NixCo100−xnanoparticles on reduced grapheneoxide nanosheets and their magnetic and catalytic properties.ACS Appl. Mater. Interfaces, 2012, 4, 2378–2386.
8.S.BaiandX.Shen*. Graphene-inorganic nanocomposites,RSC Adv., 2012,2, 64–98 (入選ESI高引頻論文).
7.S.Bai, X.Shen*, X.Zhong, Y.Liu, G.Zhu, X.XuandK.Chen.One-pot solvothermal preparation of magnetic reduced graphene oxide-ferrite composites for organic dye removal.Carbon, 2012,50, 2337–2346(入選ESI高引頻論文).
6.S.Bai, X.Shen*, G.Zhu, Z.XuandJ.Yang.In situ growth of FeNi alloy nanoflowers on reduced graphene oxide nanosheets and their magnetic properties,CrystEngComm, 2012,14, 1432–1438.
5.G. Zhu, Y. Liu, Z. Ji,S. Bai,X.Shen*andZ.Xu.Hierarchical ZnO microspheres built by sheet-like network: Large-scale synthesis and structurally enhanced catalytic performances.Mater. Chem. Phys., 2012, 132, 1065–1070.
2011年
4.S.Bai, X.Shen*, G.Zhu, Z.XuandY.Liu.Reversible phase transfer of graphene oxide and its use in the synthesis of graphene-based composite materials.Carbon,2011,49,4563–2118.
2010年
3. J. Wu,S. Bai,X.Shen*andL.Jiang.Preparation and characterization of graphene/CdS nanocomposites,Appl. Surf. Sci.,2010, 257, 747–751.
2.X.Shen*,J. Wu,S. Baiand H. Zhou. One-pot solvothermal syntheses and magnetic properties of graphene-based magnetic nanocomposites,J. Alloy. Compd.,2010, 506, 136–140.
- 柏嵩，沈小平*，石墨烯基無機納米複合材料，化學進展，2010，22，2106.
學生培養
1.指導或合作指導研究生獲2017、2018年度“研究生國家獎學金”3人次。
2.指導或合作指導研究生獲2018年度“浙江省優秀碩士論文”1人次。
3.指導或合作指導研究生獲2018年度“浙江省研究生優秀畢業生”1人次。
榮譽獎項
1.江蘇省優秀碩士論文（2013年）
2.中國科學院院長特別獎（2015年）
3.江蘇省科學技術三等獎（第五完成人，2016年）
4.中國科學院優秀博士論文獎（2018年）
